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Which of the following statement are cor...

Which of the following statement are correct regarding this equation
`Br_(2) to BrCO_(3)^(-) + Br^(-)` ?

A

Bromine is oxidised

B

Bromine is reduced

C

It is an example of disproportionation reaction

D

Bromine is neither oxidised nor reduced

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given reaction \( \text{Br}_2 \rightarrow \text{BrCO}_3^{-} + \text{Br}^{-} \) and determine which statements are correct, we can follow these steps: ### Step 1: Determine the oxidation states of bromine in the reactants and products. - In the reactant \( \text{Br}_2 \), bromine is in its elemental form, so the oxidation state is 0. - In the product \( \text{BrCO}_3^{-} \), we need to find the oxidation state of bromine. The overall charge of the ion is -1, and we can assume that the oxidation state of carbon is +4 (since it is in a carbonate ion, CO3). Therefore, we can set up the equation: \[ x + 4(-2) = -1 \implies x - 8 = -1 \implies x = +1 \] Thus, the oxidation state of bromine in \( \text{BrCO}_3^{-} \) is +1. - In the product \( \text{Br}^{-} \), the oxidation state of bromine is -1. ### Step 2: Identify oxidation and reduction processes. - Oxidation is defined as the increase in oxidation state. Here, bromine goes from 0 in \( \text{Br}_2 \) to +1 in \( \text{BrCO}_3^{-} \). Therefore, bromine is oxidized. - Reduction is defined as the decrease in oxidation state. Here, bromine goes from 0 in \( \text{Br}_2 \) to -1 in \( \text{Br}^{-} \). Therefore, bromine is reduced. ### Step 3: Determine if the reaction is a disproportionation reaction. - A disproportionation reaction occurs when the same element is both oxidized and reduced in the same reaction. Since bromine is being oxidized to \( \text{BrCO}_3^{-} \) and reduced to \( \text{Br}^{-} \), this reaction qualifies as a disproportionation reaction. ### Conclusion: Based on the analysis: 1. Bromine is oxidized (correct). 2. Bromine is reduced (correct). 3. The reaction is a disproportionation reaction (correct). 4. Any statement claiming otherwise would be incorrect. ### Final Answer: - Statements 1, 2, and 3 are correct. - Statement 4 is incorrect.
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