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Arrange the alkali metals in increasing ...

Arrange the alkali metals in increasing order of their density.

A

(a) `Li lt Na lt K lt Rb lt Cs`

B

(b) `Cs lt Rb lt K lt Na lt Li`

C

(c) `Li lt K lt Na lt Rb lt Cs`

D

(d) `K lt Na lt Li lt Rb lt Cs`

Text Solution

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The correct Answer is:
To solve the question of arranging alkali metals in increasing order of their density, we will follow these steps: ### Step 1: Understand the Alkali Metals The alkali metals include lithium (Li), sodium (Na), potassium (K), rubidium (Rb), and cesium (Cs). They are located in Group 1 of the periodic table. ### Step 2: Analyze the Trend in Density Density is defined as mass per unit volume. For elements, it can be thought of as atomic mass divided by atomic volume. As we move down the group of alkali metals: - The atomic mass increases due to the increase in atomic number. - The atomic size also increases because of the addition of electron shells. ### Step 3: Determine the Effect on Density While both atomic mass and atomic size increase down the group, the increase in atomic mass tends to dominate. This means that, generally, the density of alkali metals increases as we move down the group. ### Step 4: Identify Anomalies However, there is an anomaly between sodium and potassium: - Sodium (Na) has a higher density than potassium (K) despite potassium being lower in the group. This is due to the unusual increase in the atomic size of potassium, which decreases its density. ### Step 5: Arrange the Alkali Metals by Density Based on the trends and the anomaly: 1. Lithium (Li) - lowest density 2. Potassium (K) - lower density than sodium 3. Sodium (Na) - higher density than potassium 4. Rubidium (Rb) - higher density than sodium 5. Cesium (Cs) - highest density Thus, the correct order of increasing density is: **Li < K < Na < Rb < Cs** ### Step 6: Verify Against Options Now, we can check the provided options: - Option A: Li < Na < K < Rb < Cs (Incorrect) - Option B: Cs < Rb < K < Na < Li (Incorrect) - Option C: Li < K < Na < Rb < Cs (Correct) - Option D: K < Na < Li < Rb < Cs (Incorrect) The correct answer is **Option C: Li < K < Na < Rb < Cs**.
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