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Match the following : {:(,"Column-I",,...

Match the following `:`
`{:(,"Column-I",,"Column-II"),((A),"Velocity",(p),"Increased,"n uarr z darr),((B), "Potential Energy",(q),"Increased,"ndarrzuarr),((C ),E_(n)-E_(n-1) (E="Total energy for H atom "(n cancel(=)1)),(r ),"Decreased,"n uarr ),((D),"Separation energy (For H atom)",(s),"No change"n uarr):}`

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The correct Answer is:
To solve the matching question, we will analyze each item in Column-I and determine its relationship with the items in Column-II based on the principles of atomic structure. ### Step-by-Step Solution: 1. **Velocity (A)**: - The velocity of an electron in an atom is given by the formula \( v \propto \frac{Z}{n} \), where \( Z \) is the atomic number and \( n \) is the principal quantum number. - As \( n \) increases, \( v \) decreases (since \( v \) is inversely proportional to \( n \)). - Therefore, when \( n \) increases, the velocity decreases. - This matches with option (r) "Decreased". 2. **Potential Energy (B)**: - The potential energy of an electron in an atom is given by \( U \propto -\frac{Z}{n} \). - As \( n \) increases, the potential energy becomes less negative (increases). - Therefore, when \( n \) increases, the potential energy increases. - This matches with option (p) "Increased". 3. **Energy Difference (C) \( E_n - E_{n-1} \)**: - The energy difference between two levels in a hydrogen atom can be expressed as \( E_n - E_{n-1} \propto -\frac{Z^2}{n^2} \). - As \( n \) increases, this energy difference decreases. - Therefore, when \( n \) increases, \( E_n - E_{n-1} \) decreases. - This matches with option (r) "Decreased". 4. **Separation Energy (D)**: - The separation energy is the energy required to remove an electron from the atom and is related to the principal quantum number \( n \). - As \( n \) increases, the separation energy also increases. - Therefore, when \( n \) increases, the separation energy increases. - This matches with option (q) "Increased". ### Final Matching: - A (Velocity) → (r) "Decreased" - B (Potential Energy) → (p) "Increased" - C (E_n - E_{n-1}) → (r) "Decreased" - D (Separation Energy) → (q) "Increased" ### Summary of Matches: - A → r - B → p - C → r - D → q
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