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Resonance is not possible in...

Resonance is not possible in

A

B

C

D

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The correct Answer is:
To solve the question "Resonance is not possible in", we will analyze each of the given options to determine whether resonance can occur. ### Step-by-Step Solution: 1. **Understanding Resonance**: - Resonance involves the movement of pi electrons within a molecule. For resonance to occur, there must be: - A lone pair of electrons on one atom. - An adjacent atom with an empty orbital to accept those electrons. - The atoms involved must be in the same plane. 2. **Analyzing Option 1: CH3CH(+)O(CH3)** - In this structure, the oxygen has a lone pair of electrons and is adjacent to a carbon with a positive charge. - The lone pair on oxygen can be donated to form a double bond with the carbon, resulting in resonance. - **Conclusion**: Resonance is possible in this option. 3. **Analyzing Option 2: CH2=CH(+)NH3** - Here, nitrogen has a positive charge and does not have a lone pair of electrons. - Since nitrogen is positively charged and has only two bonds, it cannot participate in resonance because it lacks the necessary lone pair or empty orbital. - **Conclusion**: Resonance is NOT possible in this option. 4. **Analyzing Option 3: CH2=CH-NO2** - In this case, the nitrogen in the nitro group (NO2) has a positive charge, and the oxygen atoms have lone pairs. - The resonance can occur as the lone pairs on the oxygen can interact with the nitrogen, allowing for electron movement and resonance structures to form. - **Conclusion**: Resonance is possible in this option. 5. **Analyzing Option 4: CH2=CH-BH2** - Boron (B) has an empty p-orbital and can accept electrons. The carbon-carbon double bond can interact with boron. - The resonance can occur as the electron density shifts towards boron, allowing for resonance structures. - **Conclusion**: Resonance is possible in this option. ### Final Answer: - The correct answer is **Option 2: CH2=CH(+)NH3**, as resonance is not possible in this structure.
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In which of the following species resonance is possible?

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Knowledge Check

  • Resonance is an example of

    A
    forced oscillation
    B
    damped oscillation
    C
    free oscillation
    D
    none of these
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