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During the chromic acid oxidation o...

During the chromic acid oxidation of isopropyl alcohol into acetone colour of the reaction mixture changes from yellow - orange to greenish blue . The greenish blue colour is because of

A

Acetone

B

`H_(2)CrO_(4)`

C

`HCrO_(3)`

D

`Cr_^(3+)`

Text Solution

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The correct Answer is:
To solve the question regarding the color change during the chromic acid oxidation of isopropyl alcohol into acetone, we can break down the process step by step: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant in this reaction is isopropyl alcohol (C3H8O), which can be represented as CH3CHOHCH3. 2. **Identify the Oxidizing Agent**: - The oxidizing agent used is chromic acid (H2CrO4). This compound is derived from chromium trioxide (CrO3) and sulfuric acid (H2SO4) and is commonly referred to as Jones reagent. 3. **Understanding the Oxidation Process**: - In this reaction, isopropyl alcohol is oxidized to acetone (C3H6O). During this process, the chromium in chromic acid is reduced. 4. **Oxidation State Changes**: - In chromic acid (H2CrO4), chromium is in the +6 oxidation state. When it acts as an oxidizing agent and oxidizes isopropyl alcohol, it gets reduced to chromium in the +3 oxidation state (Cr^3+). 5. **Color Change Observation**: - The initial color of chromic acid (H2CrO4) is yellow-orange due to the presence of dichromate ions (Cr2O7^2-). As the reaction proceeds and chromium is reduced to Cr^3+, the color of the solution changes to greenish-blue. 6. **Conclusion**: - The greenish-blue color observed in the reaction mixture is due to the formation of chromium ions in the +3 oxidation state (Cr^3+). ### Final Answer: The greenish-blue color is because of the formation of chromium ions in the +3 oxidation state (Cr^3+) during the oxidation of isopropyl alcohol by chromic acid. ---

To solve the question regarding the color change during the chromic acid oxidation of isopropyl alcohol into acetone, we can break down the process step by step: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant in this reaction is isopropyl alcohol (C3H8O), which can be represented as CH3CHOHCH3. 2. **Identify the Oxidizing Agent**: ...
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Knowledge Check

  • Yellow coloured aquesous solution of sodium chromate changes to orange when acidified with sulphuric acid because

    A
    `H^(+)` ions convert chromate ions to dichromate ions
    B
    `H^(+)` ions react with sodium chromate to give sodium ions which turn solution orange
    C
    `Cr^(3+)` ions are liberated in the solution which turn the solution orange
    D
    sodium hydroxide is formed during the reaction which imparts orange colour to the solution.
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