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Statement -1 : Phenol and benzoic acid...

Statement -1 : Phenol and benzoic acid can be distinguished by `NaHCO_(3)`
Statement -2 Phenol releases `CO_(2)` gas from `NaHCO_(3)`

A

Statement -1 is true ,Statement -2 is True , Statement -2 is a correct explanation for Statement `-1 `

B

Statement -1 is True , Statement -2 is True Statement -2 is NOT a correct explanation for Statement `-1`

C

Statement -1 is True Statement -2 is False

D

Statement -1 is False Statement -2 is True

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements regarding phenol and benzoic acid in relation to their behavior with sodium bicarbonate (NaHCO₃). ### Step-by-Step Solution: 1. **Understanding the Reactivity of Benzoic Acid:** - Benzoic acid (C₆H₅COOH) is a carboxylic acid and is known to be a stronger acid compared to phenol. - When benzoic acid reacts with sodium bicarbonate, it can donate a proton (H⁺) to form sodium benzoate and carbonic acid (H₂CO₃), which decomposes to release carbon dioxide (CO₂) gas. - Reaction: \[ C_6H_5COOH + NaHCO_3 \rightarrow C_6H_5COONa + H_2O + CO_2 \uparrow \] 2. **Understanding the Reactivity of Phenol:** - Phenol (C₆H₅OH) is a weaker acid compared to benzoic acid. It does not readily donate a proton to sodium bicarbonate. - Therefore, phenol does not react with sodium bicarbonate, and no gas is released when phenol is treated with NaHCO₃. 3. **Evaluating Statement 1:** - Statement 1 claims that phenol and benzoic acid can be distinguished by NaHCO₃. This is true because only benzoic acid will react and release CO₂ gas, while phenol will not react. - Conclusion: **Statement 1 is true.** 4. **Evaluating Statement 2:** - Statement 2 claims that phenol releases CO₂ gas from NaHCO₃. This is false because phenol does not react with NaHCO₃ and hence does not release any gas. - Conclusion: **Statement 2 is false.** ### Final Conclusion: - Statement 1 is true, and Statement 2 is false.

To solve the question, we need to analyze both statements regarding phenol and benzoic acid in relation to their behavior with sodium bicarbonate (NaHCO₃). ### Step-by-Step Solution: 1. **Understanding the Reactivity of Benzoic Acid:** - Benzoic acid (C₆H₅COOH) is a carboxylic acid and is known to be a stronger acid compared to phenol. - When benzoic acid reacts with sodium bicarbonate, it can donate a proton (H⁺) to form sodium benzoate and carbonic acid (H₂CO₃), which decomposes to release carbon dioxide (CO₂) gas. - Reaction: ...
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Knowledge Check

  • Assertion : Phenol and benzoic acid can be distinguished by Na_(2)CO_(3). Reason : Benzoic acid is stronger acid than phenol, hence reacts with Na_(2)CO_(3) .

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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