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X+NH(3)overset(50^(@)C)toYoverset(H^(+)/...

`X+NH_(3)overset(50^(@)C)toYoverset(H^(+)//H_(2)O)toH_(2)N-CH_(2)COOH`
Compound X is

A

Chloroacetic acid

B

Bromoacetic acid

C

outside the helix

D

Acetic acid

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the compound X that reacts with ammonia (NH₃) to form compound Y, which then undergoes hydrolysis to produce an amino acid (specifically, H₂N-CH₂COOH). ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction involves a compound X reacting with ammonia (NH₃) at 50°C to form compound Y, which subsequently undergoes hydrolysis to yield an amino acid. 2. **Identifying the Structure of Compound Y**: The final product after hydrolysis is H₂N-CH₂COOH, which is glycine, an amino acid. This indicates that compound Y must be an intermediate that can lead to the formation of glycine. 3. **Analyzing Possible Compounds for X**: We need to consider compounds that can react with ammonia to form an amine (which will be compound Y) and then can be hydrolyzed to yield glycine. 4. **Considering Bromoacetic Acid**: - Bromoacetic acid (BrCH₂COOH) is an alpha halo acid. - When it reacts with ammonia, the bromine atom (a good leaving group) is replaced by an amino group (NH₂), leading to the formation of NH₂CH₂COOH (glycine) after hydrolysis. - The reaction can be summarized as: \[ \text{BrCH}_2\text{COOH} + \text{NH}_3 \rightarrow \text{NH}_2\text{CH}_2\text{COOH} + \text{HBr} \] 5. **Considering Other Options**: - **Chloroacetic Acid (ClCH₂COOH)**: Similar to bromoacetic acid, but chlorine is a poorer leaving group than bromine. While it can also react with ammonia, the reaction is less favorable compared to bromoacetic acid. - **Acetic Acid (CH₃COOH)**: This does not have a halogen to replace with an amino group and would form an amide instead, which is not the desired product. - **Other Options**: Any other compounds that do not contain a good leaving group or do not lead to the formation of an amino acid after hydrolysis can be ruled out. 6. **Conclusion**: After analyzing the options, the best candidate for compound X is **bromoacetic acid** because it can effectively react with ammonia to form glycine after hydrolysis. ### Final Answer: Compound X is **bromoacetic acid (BrCH₂COOH)**.
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