Home
Class 12
CHEMISTRY
Consider the data given below for hypoth...

Consider the data given below for hypothetical reaction `A rarr X`
`{:(,"Time (s)",,"Rate of the reaction"(mol L^(-1)s^(-1))),(,0,,1.60xx10^(-2)),(,10,,1.60xx10^(-2)),(,20,,1.60xx10^(-2)),(,30,,1.59xx10^(-2)):}`
From the above data, the order of reaction is:

A

Zero

B

1

C

2

D

3

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction from the provided data, we will analyze the relationship between the rate of the reaction and the concentration of the reactant over time. ### Step-by-Step Solution: 1. **Understanding the Data**: - We have the following data: - At time 0 seconds, the rate of reaction is \(1.60 \times 10^{-2}\) mol L\(^{-1}\) s\(^{-1}\). - At time 10 seconds, the rate is still \(1.60 \times 10^{-2}\) mol L\(^{-1}\) s\(^{-1}\). - At time 20 seconds, the rate remains \(1.60 \times 10^{-2}\) mol L\(^{-1}\) s\(^{-1}\). - At time 30 seconds, the rate is \(1.59 \times 10^{-2}\) mol L\(^{-1}\) s\(^{-1}\), which is approximately the same as the previous rates. 2. **Analyzing the Rates**: - The rate of the reaction remains approximately constant (around \(1.60 \times 10^{-2}\) mol L\(^{-1}\) s\(^{-1}\)) despite the passage of time. This indicates that the rate does not change significantly as the concentration of reactant A decreases. 3. **Understanding Reaction Order**: - The general rate equation for a reaction is given by: \[ \text{Rate} = k \cdot [A]^n \] where \(k\) is the rate constant, \([A]\) is the concentration of reactant A, and \(n\) is the order of the reaction. 4. **Determining the Order**: - Since the rate of reaction remains constant even as the concentration of A decreases, we can infer that the rate does not depend on the concentration of A. - This implies that \(n = 0\) because if the concentration of A does not affect the rate, the reaction behaves as a zero-order reaction. 5. **Conclusion**: - Therefore, based on the data provided, the order of the reaction is 0. ### Final Answer: The order of the reaction is **0** (Option A). ---
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (SECTION C : Previous Year Questions)|62 Videos
  • CHEMICAL KINETICS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (SECTION D : Assertion - Reason Type Questions)|15 Videos
  • CHEMICAL KINETICS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (SECTION A : Objective Type Questions)|50 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    AAKASH INSTITUTE ENGLISH|Exercise Assignment Section J (Aakash Challengers Questions)|10 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    AAKASH INSTITUTE ENGLISH|Exercise Assignment ( SECTION - A)|45 Videos

Similar Questions

Explore conceptually related problems

The experiment data for the reaction 2A + B_(2) rarr 2AB is |{:("Experiment",[A] M,[B_(2)] M,"Initial rate" (mol L^(-1) s^(-1)),),(I,0.50,0.5,1.6 xx 10^(-4),),(II,0.50,1.0,3.2 xx 10^(-4),),(III,1.00,1.0,3.2 xx 10^(-4),):}| Write the most probable rate equation for the reaction giving reason for your answer.

The experiment data for the reaction 2A + B_(2) rarr 2AB is |{:("Experiment",[A] M,[B_(2)] M,"Initial rate" (mol L^(-1) s^(-1)),),(I,0.50,0.5,1.6 xx 10^(-4),),(II,0.50,1.0,3.2 xx 10^(-4),),(III,1.00,1.0,3.2 xx 10^(-4),):}| Write the most probable rate equation for the reacting giving reason for you answer.

Calculate the order of the reaction in A and B :- {:(A,,,B,,,Rate),(("mol"//1),,,("mol"//1),,,),(0.05,,,0.05,,,1.2xx10^(-3)),(0.10,,,0.05,,,2.4xx10^(-3)),(0.05,,,0.10,,,1.2xx10^(-3)):}

For the decompoistion of HI at 1000 K(2HI rarr H_(2)+I_(2)) , following data were obtained: |{:([HI] (M),"Rate of decomposition of HI" (mol L^(-1) s^(-1))),(0.1,2.75 xx 10^(-8)),(0.2,11 xx 10^(-8)),(0.3,24.75 xx 10^(-8)):}| The order of reaction is

For the decompoistion of HI at 1000 K(2HI rarr H_(2)+I_(2)) , following data were obtained: |{:([HI] (M),"Rate of decomposition of HI" (mol L^(-1) s^(-1))),(0.1,2.75 xx 10^(-8)),(0.2,11 xx 10^(-8)),(0.3,24.75 xx 10^(-8)):}| The order of reaction is

In data given below. {:(,[A],[B],"rate"),(,mol//L,mol//L,mol L ^(-1)s^(-1)),(a., 0.02,1.2,3.0xx10^(-3)),(b.,0.04,2.4,6.0xx10^(-3)):} The reaction may be

The reaction of A_(2) and B_(2) follows the equation A_(2)(g)+B_(2)(g)to2AB(g) The following data were observed {:(,[A_(2)]_(0),[B_(2)]_(0),"Initial rate of appearance of AB(g)(in" Ms^(-1)),(,0.10,0.10,2.5xx10^(-4)),(,0.20,0.10,5xx10^(-4)),(,0.20,0.20,10xx10^(-4)):} The value of rate constatnt for the above reaction is :

For a hypothetical reaction A + B rarr C , suggest the rate law and order form the following data: |{:("Experiment",[A] (mol L^(-1)),[B] (mol L^(-1)),"Refer of reaction" (mol L^(-1) s^(-1)),),(I,0.25,0.25,3.0 xx 10^(-3),),(II,0.50,0.25,6.0 xx 10^(-3),),(III,0.50,0.50,1.20 xx 10^(-2),):}|

For a reaction 2NO(g) + 2H_(2)(g) rarr N_(2)(g)+2H_(2)O(g) the following data were obtained: |{:(,[NO] (mol L^(-1)),[H_(2)] (mol L^(-1)),"Rate" (mol L^(-1) s^(-1))),(1.,5 xx 10^(-3),2.5 xx 10^(-3),3 xx 10^(-5)),(2.,15 xx 10^(-3),2.5 xx 10^(-3),9xx10^(-5)),(3.,15 xx 10^(-3),10 xx 10^(-3),3.6 xx 10^(-4)):}| (a) Calculating the order of reactions. (b) Find the rate constant. (c ) Find the initial rate if [NO] = [H_(2)] = 8.0 xx 10^(-3) M

For the hypothetical reaction 2A + B rarr Products following data obtained: |{:("Experiment number","Initial conc of (A)" (mol L^(-1)),"Initial conc of (B)" (mol L^(-1)),"Initial rate mol" L^(-1) s^(-1),),(1,0.10,0.20,3 xx 10^(2),),(2,0.30,0.40,3.6 xx 10^(10^(3)),),(3,0.30,0.80,1.44 xx 10^(4),),(4,0.10,0.40,...,),(5,0.20,0.60,...,),(6,0.30,1.20,...,):}| Find out how the rate of the reaction depends upon the concentration of A and B and fill in the blanks given in the table.

AAKASH INSTITUTE ENGLISH-CHEMICAL KINETICS-ASSIGNMENT (SECTION B : Objective Type Questions)
  1. Consider the data given below for hypothetical reaction A rarr X {:...

    Text Solution

    |

  2. The graph between log k versus 1//T is a straight line.

    Text Solution

    |

  3. The temperature coefficient of most of the reactions lies between

    Text Solution

    |

  4. If the volume of the vessel in which the reaction 2NO+O2 rarr2NO2 is...

    Text Solution

    |

  5. For the raction A+Brarr products, it is found that order of A is 2 and...

    Text Solution

    |

  6. Nitric oxide (NO) reacts with oxygen to produce nitrogen dioxide 2NO...

    Text Solution

    |

  7. For the first order reaction, the taken to reduce the initial concentr...

    Text Solution

    |

  8. The rate of the reaction 2N(2)O(5) to 4NO(2) + O(2) can be written...

    Text Solution

    |

  9. For the reaction , N2O4(g)underset(K2)overset(K1)hArr2NO2(g), the rat...

    Text Solution

    |

  10. For a homogeneous gaseous reaction A rarr B + C + D , the initial pres...

    Text Solution

    |

  11. form the gaseous reaction 2A + B(2) rarr 2AB, the following rate dat...

    Text Solution

    |

  12. The inversion of a sugar follows first order rate equation which can b...

    Text Solution

    |

  13. Which of the following is correct

    Text Solution

    |

  14. The rate constant for a reaction is 1.5 xx 10^(-7) at 50^(@)C and 4.5...

    Text Solution

    |

  15. In Arrhenius equation , k=Ae^(Ea/(RT)) , A may be termed as rate const...

    Text Solution

    |

  16. The rate constant of the production of 2B (g) by the reaction , A(g)ov...

    Text Solution

    |

  17. Two substances A and B are present such that [A(0)]=4[B(0] and half-l...

    Text Solution

    |

  18. If the rate of reaction increases by 27 times , when temperature is in...

    Text Solution

    |

  19. the reaction A to B follows first order Kinetics the time taken...

    Text Solution

    |

  20. If find B%

    Text Solution

    |