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Molecule which follows octet rule...

Molecule which follows octet rule

A

`CIO_(2)`

B

NO

C

`NO_(2)`

D

`N_(2)O_(3)`

Text Solution

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The correct Answer is:
To determine which molecule follows the octet rule, we need to analyze the valence electrons of each atom in the molecule and see if they achieve a total of 8 electrons in their outermost shell. ### Step-by-Step Solution: 1. **Understanding the Octet Rule**: The octet rule states that atoms tend to form bonds in a way that gives them 8 electrons in their valence shell, achieving a noble gas configuration. 2. **Analyzing ClO2 (Chlorine Dioxide)**: - Chlorine (Cl) is in group 17 and has 7 valence electrons. - Each Oxygen (O) is in group 16 and has 6 valence electrons. - Total for ClO2: - Cl: 7 electrons - O1: 6 electrons - O2: 6 electrons - Total = 7 + 6 + 6 = 19 electrons - Chlorine has 11 electrons around it (after bonding), which does not satisfy the octet rule. 3. **Analyzing NO (Nitric Oxide)**: - Nitrogen (N) is in group 15 and has 5 valence electrons. - Oxygen (O) has 6 valence electrons. - Total for NO: - N: 5 electrons - O: 6 electrons - Total = 5 + 6 = 11 electrons - Nitrogen has 7 electrons around it after bonding, which does not satisfy the octet rule. 4. **Analyzing NO2 (Nitrogen Dioxide)**: - Nitrogen (N) has 5 valence electrons. - Each Oxygen (O) has 6 valence electrons. - Total for NO2: - N: 5 electrons - O1: 6 electrons - O2: 6 electrons - Total = 5 + 6 + 6 = 17 electrons - Nitrogen has 9 electrons around it after bonding, which does not satisfy the octet rule. 5. **Analyzing N2O3 (Dinitrogen Trioxide)**: - Each Nitrogen (N) has 5 valence electrons. - Each Oxygen (O) has 6 valence electrons. - Total for N2O3: - N1: 5 electrons - N2: 5 electrons - O1: 6 electrons - O2: 6 electrons - O3: 6 electrons - Total = 5 + 5 + 6 + 6 + 6 = 28 electrons - Each atom: - Each O has 8 electrons around it. - Each N has 8 electrons around it. - All atoms satisfy the octet rule. 6. **Conclusion**: The molecule that follows the octet rule is **N2O3** because all atoms in this molecule have 8 electrons in their outermost shell.
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Knowledge Check

  • Which one of the following exceeds octet rule ?

    A
    The incomplete octet of central atom
    B
    An odd number of electrons on central atom
    C
    Expanded octed of the central atom
    D
    All of these
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