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In the following questions, a statement ...

In the following questions, a statement of assertion (A) is followed by a statement of reason (R )
A : `CO_(2) ` is resonance stabilized molecule.
R : Bond length of C-O I `CO_(2)` is intemediate of single and double bond length.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements , then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion (A) and reason (R) provided in the question, we can break down the solution into the following steps: ### Step 1: Understand the Assertion The assertion states that CO₂ is a resonance-stabilized molecule. This means that the actual structure of CO₂ is a hybrid of multiple resonance forms, which contributes to its stability. **Hint:** Recall that resonance occurs when a molecule can be represented by two or more valid Lewis structures. ### Step 2: Draw the Lewis Structure of CO₂ The Lewis structure of CO₂ shows that carbon (C) is double-bonded to each oxygen (O) atom. The structure can be represented as: ``` O=C=O ``` Each oxygen has two lone pairs of electrons. **Hint:** Remember that in CO₂, carbon is the central atom, and it forms double bonds with both oxygen atoms. ### Step 3: Identify Resonance Forms In CO₂, the double bonds can shift, leading to different resonance structures. For example: 1. One resonance form can have a double bond between C and one O, and a single bond with a positive charge on C and a negative charge on the other O. 2. Another resonance form can have the double bond shift to the other O, resulting in a similar charge distribution. **Hint:** Think about how the movement of electrons can create different valid structures for the same molecule. ### Step 4: Evaluate the Reason The reason states that the bond length of C-O in CO₂ is intermediate between single and double bond lengths. This is incorrect because the bond in CO₂ is primarily a double bond, and the bond lengths are not intermediate between single and double bonds. **Hint:** Recall the typical bond lengths for single, double, and triple bonds. A double bond is shorter than a single bond, not intermediate. ### Step 5: Conclusion - The assertion (A) is true because CO₂ is resonance-stabilized. - The reason (R) is false because the bond length in CO₂ is not intermediate between single and double bond lengths; it is closer to that of a double bond. Thus, the correct conclusion is that the assertion is true, but the reason is false. **Final Answer:** Assertion (A) is true, and Reason (R) is false.
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