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A : In alkaline medium, KMnO(4) acts as ...

A : In alkaline medium, `KMnO_(4)` acts as powerful oxidising agent.
R : `KMnO_(4)` reduces to give `Mn^(2+)` in alkaline medium.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reason provided regarding the behavior of potassium permanganate (KMnO₄) in alkaline medium. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that in alkaline medium, KMnO₄ acts as a powerful oxidizing agent. - To evaluate this, we need to consider the behavior of KMnO₄ in alkaline conditions. 2. **Behavior of KMnO₄ in Alkaline Medium**: - In alkaline medium, KMnO₄ exists as MnO₄⁻ (permanganate ion). - The reduction of MnO₄⁻ in alkaline medium leads to the formation of MnO₄²⁻ (manganate ion). 3. **Determining Oxidation States**: - Calculate the oxidation state of manganese in both MnO₄⁻ and MnO₄²⁻. - For MnO₄⁻: - Let the oxidation state of manganese be X. - The equation becomes: X + 4(-2) = -1 (charge of MnO₄⁻). - Thus, X - 8 = -1 → X = +7. - For MnO₄²⁻: - Let the oxidation state of manganese be Y. - The equation becomes: Y + 4(-2) = -2 (charge of MnO₄²⁻). - Thus, Y - 8 = -2 → Y = +6. 4. **Change in Oxidation State**: - The change in oxidation state from MnO₄⁻ to MnO₄²⁻ is from +7 to +6, which is a change of 1. - This indicates that KMnO₄ is not acting as a strong oxidizing agent in alkaline medium, as it only changes its oxidation state by 1. 5. **Evaluating the Reason**: - The reason states that KMnO₄ reduces to give Mn²⁺ in alkaline medium. - This is incorrect because KMnO₄ does not reduce to Mn²⁺ in alkaline medium; it reduces to MnO₄²⁻ instead. 6. **Conclusion**: - Both the assertion and the reason are false. - Therefore, the correct answer to the question is that both statements are false. ### Final Answer: Both the assertion and reason are false.
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Knowledge Check

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    A
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    C
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