Home
Class 12
CHEMISTRY
As the dilution of an electrolyte increa...

As the dilution of an electrolyte increases
(a) Sepcific conductance decreases
(b)Molar conductance decreases
(c)Resistance increases
(d)No change takes place in conductance As the dilution of an electrolyte increases

A

Sepcific conductance decreases

B

Molar conductance decreases

C

Resistance increases

D

No change takes place in conductance

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the effects of dilution on an electrolyte, let's analyze each option step by step. ### Step-by-Step Solution: 1. **Understanding Specific Conductance (κ)**: - Specific conductance (κ) is defined as the conductance of a solution between two electrodes. It is influenced by the number of ions present in the solution. - As the electrolyte is diluted, the concentration of ions decreases. Since specific conductance is directly proportional to the number of ions available to conduct electricity, it follows that: \[ \text{Specific Conductance (κ) decreases} \] - Therefore, option (a) is **correct**. 2. **Understanding Molar Conductance (Λm)**: - Molar conductance (Λm) is defined as the conductance of the electrolyte solution per mole of the electrolyte. It is given by the formula: \[ \Lambda_m = \frac{\kappa \times 1000}{C} \] where C is the molarity of the solution. - As the solution is diluted, the molarity (C) decreases. Since molar conductance is inversely proportional to molarity, the decrease in molarity leads to an increase in molar conductance: \[ \text{Molar Conductance (Λm) increases} \] - Therefore, option (b) is **incorrect**. 3. **Understanding Resistance (R)**: - Resistance in a solution is affected by the interactions between solute and solvent molecules. As the electrolyte is diluted, these interactions decrease, leading to a decrease in resistance: \[ \text{Resistance (R) decreases} \] - Therefore, option (c) is **incorrect**. 4. **Conductance (G)**: - Conductance is defined as the reciprocal of resistance: \[ G = \frac{1}{R} \] - Since resistance decreases with dilution, conductance must increase: \[ \text{Conductance (G) increases} \] - Therefore, option (d) is **incorrect**. ### Final Answers: - (a) Specific conductance decreases: **Correct** - (b) Molar conductance decreases: **Incorrect** - (c) Resistance increases: **Incorrect** - (d) No change takes place in conductance: **Incorrect**
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

The plot of molar conductance vs sqrt(C) in strong electrolyte , is

The molar conductivity of strong electrolyte

Knowledge Check

  • Which of the following decreases on dilution of electrolyte solution ?

    A
    Equivalent conductance
    B
    Molar conductance
    C
    Specific conductance
    D
    Conductance
  • Assertion: The conductivity of electrolytic soutions increase with increase of temperture. Reason: Electronic conductance decrease with increase of temperture.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion .
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion .
    C
    If assertion is true but reason is false .
    D
    If both assertion and reason are false .
  • Similar Questions

    Explore conceptually related problems

    At infinite dilution of an electrolyte, the equivalent conductance of cations at anions are ………………… of each other.

    (i) Specific conductance decreases with dilution whereas equivalent conductance increses with dilution. Why ? (ii) State the Faraday's second law of electrolysis.

    Why ac is used in place of dc in measuring the conductance of electrolytes ?

    An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to:

    Give a reason for the following: Specific conductance decreases with dilution whereas equivalent conductance increases with dilution.

    By diluting a weak electrolyte, specific conductivity (K_(c)) and equivalent conductivity (lamda_(c)) change as