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Why does magnesium form Mg^(2+) and not ...

Why does magnesium form `Mg^(2+)` and not `Mg^(+)`?

A

Magnesium (II) is insoluble in water

B

Commonly higher oxidation states are preferred by metals

C

lonic radius of Mg(II) is samller than that of Mg(I)

D

High hydration energy as well as high latice

Text Solution

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The correct Answer is:
To understand why magnesium forms \( \text{Mg}^{2+} \) instead of \( \text{Mg}^{+} \), let's analyze the electronic configuration and the principles governing ion formation. ### Step-by-Step Solution: 1. **Identify the Atomic Number and Electronic Configuration of Magnesium**: - Magnesium (Mg) has an atomic number of 12. - Its electronic configuration is \( 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \). **Hint**: Recall that the atomic number indicates the number of protons and electrons in a neutral atom. 2. **Determine the Valence Electrons**: - The outermost shell (n=3) of magnesium contains 2 electrons in the \( 3s \) subshell. **Hint**: The number of valence electrons can be found by looking at the highest energy level in the electronic configuration. 3. **Understanding the Octet Rule**: - The octet rule states that atoms tend to gain, lose, or share electrons to achieve a full outer shell, typically consisting of 8 electrons. **Hint**: Consider how atoms achieve stability through electron transfer. 4. **Electron Loss and Ion Formation**: - Magnesium can lose its 2 valence electrons to achieve a stable electronic configuration similar to neon (the nearest noble gas), which has a full outer shell of 8 electrons. **Hint**: Think about the stability of noble gases and how losing electrons can help achieve that stability. 5. **Formation of \( \text{Mg}^{2+} \)**: - By losing 2 electrons, magnesium forms the ion \( \text{Mg}^{2+} \). - The formation of \( \text{Mg}^{+} \) would leave it with only 11 electrons, resulting in an unstable configuration. **Hint**: Consider the energy required to remove electrons and how it relates to stability. 6. **Lattice Energy and Hydration Energy**: - The formation of \( \text{Mg}^{2+} \) is favored due to high lattice energy and hydration energy associated with the \( \text{Mg}^{2+} \) ion compared to \( \text{Mg}^{+} \). **Hint**: Lattice energy is the energy released when ions form a solid lattice, while hydration energy is the energy released when ions are solvated by water. ### Conclusion: Magnesium forms \( \text{Mg}^{2+} \) instead of \( \text{Mg}^{+} \) because it loses 2 electrons to achieve a stable octet configuration, which is energetically favorable due to high lattice and hydration energies.
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