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A: FeCl(3), reacts with KCNS to give blo...

A: `FeCl_(3)`, reacts with KCNS to give blood red colour.
R: `FeCl_(3)`, reacts with KCNS to form potassium ferro-ferricyanide

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that `FeCl3` reacts with `KCNS` to give a blood red color. - **Explanation**: Ferric chloride (`FeCl3`) reacts with potassium thiocyanate (`KCNS`) to form ferric thiocyanate (`Fe(SCN)3`), which is known to produce a blood red color in solution. ### Step 2: Understand the Reaction The reaction can be represented as follows: \[ FeCl_3 + 3 KCNS \rightarrow Fe(SCN)_3 + 3 KCl \] - **Explanation**: In this reaction, one mole of ferric chloride reacts with three moles of potassium thiocyanate to produce one mole of ferric thiocyanate and three moles of potassium chloride. ### Step 3: Analyze the Reason The reason states that `FeCl3` reacts with `KCNS` to form potassium ferro-ferricyanide. - **Explanation**: This statement is incorrect. The product formed from the reaction of `FeCl3` and `KCNS` is ferric thiocyanate, not potassium ferro-ferricyanide. Potassium ferro-ferricyanide would involve cyanide ions (CN⁻), not thiocyanate ions (SCN⁻). ### Conclusion - **Assertion**: True (FeCl3 reacts with KCNS to give a blood red color). - **Reason**: False (It does not form potassium ferro-ferricyanide; it forms ferric thiocyanate). ### Final Answer The assertion is true, but the reason is false.
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AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
  1. A: FeCl(3), reacts with KCNS to give blood red colour. R: FeCl(3), re...

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  2. Assertion : Boiling point of p-nitrophenol is greater than that of o-n...

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  3. A : When C(2) H(5) - O- CH(3) is reacted with one mole of Hl then C(2...

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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. Phenol is less acidic than........... .

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : bond angle in ether is slightly greater than normal tetrahedral an...

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  14. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  15. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  16. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  17. A : In esterification reaction alcohol act as nucleophile . R : ...

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  18. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  19. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  20. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

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  21. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

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