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A: The energy gap Delta(t)=(4)/(9)Delta(...

A: The energy gap `Delta_(t)=(4)/(9)Delta_(0)`
R: `Delta_(0)` is always greater than `Delta_(t)`, for same metal ion and ligand.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

) If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion (A) and the reason (R) provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the energy gap \( \Delta_t = \frac{4}{9} \Delta_0 \). - This is a known relationship in coordination chemistry where \( \Delta_t \) is the splitting energy for tetrahedral complexes and \( \Delta_0 \) is the splitting energy for octahedral complexes. 2. **Understanding the Reason (R)**: - The reason states that \( \Delta_0 \) is always greater than \( \Delta_t \) for the same metal ion and ligand. - This is also true, as tetrahedral complexes typically have a smaller splitting energy compared to octahedral complexes. The relationship can be expressed as \( \Delta_t = \frac{2}{3} \Delta_0 \), which implies \( \Delta_0 > \Delta_t \). 3. **Evaluating the Assertion**: - The assertion is correct because it accurately describes the relationship between the tetrahedral and octahedral splitting energies. 4. **Evaluating the Reason**: - The reason is also correct as it states that \( \Delta_0 \) is greater than \( \Delta_t \). 5. **Conclusion**: - While both the assertion and reason are correct, the reason does not provide a correct explanation for the assertion. The assertion is a specific quantitative relationship, while the reason is a general statement about the relative sizes of the splitting energies. ### Final Answer: - The correct option is **B**: Both A and R are correct, but R is not the correct explanation of A.
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