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A: The energy gap Delta(t)=(4)/(9)Delta(...

A: The energy gap `Delta_(t)=(4)/(9)Delta_(0)`
R: `Delta_(0)` is always greater than `Delta_(t)`, for same metal ion and ligand.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

) If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4)

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The correct Answer is:
To solve the question, we need to analyze both the assertion (A) and the reason (R) provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the energy gap \( \Delta_t = \frac{4}{9} \Delta_0 \). - This is a known relationship in coordination chemistry where \( \Delta_t \) is the splitting energy for tetrahedral complexes and \( \Delta_0 \) is the splitting energy for octahedral complexes. 2. **Understanding the Reason (R)**: - The reason states that \( \Delta_0 \) is always greater than \( \Delta_t \) for the same metal ion and ligand. - This is also true, as tetrahedral complexes typically have a smaller splitting energy compared to octahedral complexes. The relationship can be expressed as \( \Delta_t = \frac{2}{3} \Delta_0 \), which implies \( \Delta_0 > \Delta_t \). 3. **Evaluating the Assertion**: - The assertion is correct because it accurately describes the relationship between the tetrahedral and octahedral splitting energies. 4. **Evaluating the Reason**: - The reason is also correct as it states that \( \Delta_0 \) is greater than \( \Delta_t \). 5. **Conclusion**: - While both the assertion and reason are correct, the reason does not provide a correct explanation for the assertion. The assertion is a specific quantitative relationship, while the reason is a general statement about the relative sizes of the splitting energies. ### Final Answer: - The correct option is **B**: Both A and R are correct, but R is not the correct explanation of A.
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Consider the following satements : S_(1): Generally square planare complexes show geometrical isomerism but do not exhibit optical isomerism because thy do not possess plane of symmetry . S_(2): Delta_(t)=(4)/(9)Delta_(0) S_(3) : In octahedral complexes each electron entering teh t_(2g) orbitals stabilizes the complex ion by 0.4 Delta_(0) and each electron entering teh e_(g) orbital destabilizes the complex by an amount of 0.6 Delta_(0) Select the correct statement from the codes given below.

If Delta_1=|(1,0),(a,b)| and Delta_2=|(1,0),(c,d)| , then Delta_2Delta_1 is equal to :

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A change in the free energy of a system at constant temperature and pressure will be: Delta_(sys)G = Delta_(sys)H -T Delta_(sys)S At constant temperature and pressure Delta_(sys) G lt 0 (spontaneous) Delta_(sys)G = 0 (equilibrium) Delta_(sys)G gt 0 (non-spontaneous) If both DeltaH and Deltas are negative, the reaction will be spontaneous

A change in the free energy of a system at constant temperature and pressure will be: Delta_(sys)G = Delta_(sys)H -T Delta_(sys)S At constant temperature and pressure Delta_(sys) G lt 0 (spontaneous) Delta_(sys)G = 0 (equilibrium) Delta_(sys)G gt 0 (non-spontaneous) The free enegry for a reaction having DeltaH = 31400 cal, DeltaS = 32 cal K^(-1) mol^(-1) at 1000^(@)C is

A change in the free energy of a system at constant temperature and pressure will be: Delta_(sys)G = Delta_(sys)H -T Delta_(sys)S At constant temperature and pressure Delta_(sys) G lt 0 (spontaneous) Delta_(sys)G = 0 (equilibrium) Delta_(sys)G gt 0 (non-spontaneous) For a spontaneous reaction DeltaG , equilibrium K and E_(cell)^(Theta) will be, respectively

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AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  3. A : When C(2) H(5) - O- CH(3) is reacted with one mole of Hl then C(2...

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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. Phenol is less acidic than........... .

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : bond angle in ether is slightly greater than normal tetrahedral an...

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  14. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  15. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  16. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  17. A : In esterification reaction alcohol act as nucleophile . R : ...

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  18. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  19. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  20. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

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  21. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

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