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A : Ozonolysis of benzene gives ethanal....

A : Ozonolysis of benzene gives ethanal.
R : Benzene is an antiaromatic compound.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correctness of the assertion and reason provided in the question, we need to analyze both statements carefully. ### Step 1: Analyze the Assertion The assertion states that "Ozonolysis of benzene gives ethanal." - Ozonolysis is a reaction where ozone (O3) reacts with alkenes or alkynes to form carbonyl compounds (aldehydes or ketones). - Benzene (C6H6) is an aromatic compound with a stable structure due to resonance. - When benzene undergoes ozonolysis, it does not directly yield ethanal (acetaldehyde, CH3CHO). Instead, ozonolysis of benzene typically leads to the formation of various carbonyl compounds, but not specifically ethanal. **Conclusion for Assertion:** The assertion is **incorrect**. ### Step 2: Analyze the Reason The reason states that "Benzene is an antiaromatic compound." - Benzene has a planar structure and contains 6 π electrons. - According to Huckel's rule, a compound is aromatic if it has (4n + 2) π electrons, where n is a non-negative integer. For benzene, n = 1, thus it has 6 π electrons (4(1) + 2 = 6). - This means benzene is **aromatic**, not antiaromatic. Antiaromatic compounds typically have 4n π electrons, which is not the case for benzene. **Conclusion for Reason:** The reason is also **incorrect**. ### Final Conclusion Both the assertion and the reason are incorrect. Therefore, the correct option is that neither the assertion nor the reason is true.
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Knowledge Check

  • Nitration of benzene is

    A
    nucleophilic substitution
    B
    nucleophilic addition
    C
    electrophilic substitution
    D
    free radical substitution.
  • Choose the compounds below that are antiaromatic :

    A
    B
    C
    D
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