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Allylic halides are...

Allylic halides are

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**Step-by-Step Solution:** 1. **Definition of Allylic Halides:** Allylic halides are organic compounds that contain a halogen atom (such as fluorine, chlorine, bromine, or iodine) bonded to a carbon atom that is adjacent to a carbon-carbon double bond (C=C). 2. **Structure of Allylic Halides:** In terms of hybridization, the carbon atom to which the halogen is attached is typically sp³ hybridized. This means that it is bonded to four other atoms, including the halogen and possibly hydrogen or other carbon atoms. 3. **Identification of Allylic Carbon:** The carbon atom that is directly bonded to the halogen is referred to as the allylic carbon. It is important to note that this carbon is adjacent to the carbon that is part of the double bond. 4. **Examples of Allylic Halides:** For example, consider the structure of an allylic halide: - If we have a double bond between two carbon atoms (C=C), and one of the carbons has a halogen (X) attached to it, this compound is classified as an allylic halide. - An example structure could be CH2=CH-CH2X, where X is a halogen. 5. **Conclusion:** Therefore, allylic halides can be summarized as compounds where a halogen is bonded to an sp³ hybridized carbon that is adjacent to a carbon-carbon double bond. ---
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Benzylic halides are

SN^(2) reaction is a bimolecular reaction which takes places by the formation of T.S. Veolcity of the reaction depends on the concentration of the substrate as well as the nucleophile. The reaction is favoureed by strong Nu^(o-) and in the presence of polar aprotic sovlent, optically active halides give. Walken inversion by SN^(2) mechanism. The presence of hero group (atom) at beta-C atom, unsaturation at beta-C and (-overset(O)overset(||)(C)-) group at alpha-C atomn favor SN^(2) mechanism. Allyl halides and benzyl halides give SN^(1) and SN^(2) reactions. Allyl halides alos give SN^(2) mechanism EDG at ortho- and para- postions in benzyl halides favors SN^(1) mechanism, wheras EWG favors SN^(2) mechanism. Which of the following will give SN^(2) mechanism?

Knowledge Check

  • Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to

    A
    formation of a less stable carbonium ion in aryl halides
    B
    resonance stabilisation in ary halides
    C
    presence of double bonds in alkyl halides
    D
    inductive effect in aryl halides.
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    SN^(2) reaction is a bimolecular reaction which takes places by the formation of T.S. Veolcity of the reaction depends on the concentration of the substrate as well as the nucleophile. The reaction is favoureed by strong Nu^(o-) and in the presence of polar aprotic sovlent, optically active halides give. Walken inversion by SN^(2) mechanism. The presence of hero group (atom) at beta-C atom, unsaturation at beta-C and (-overset(O)overset(||)(C)-) group at alpha-C atomn favor SN^(2) mechanism. Allyl halides and benzyl halides give SN^(1) and SN^(2) reactions. Allyl halides alos give SN^(2) mechanism EDG at ortho- and para- postions in benzyl halides favors SN^(1) mechanism, wheras EWG favors SN^(2) mechanism. Which of the following will give Walden inversion ?

    SN^(2) reaction is a bimolecular reaction which takes places by the formation of T.S. Veolcity of the reaction depends on the concentration of the substrate as well as the nucleophile. The reaction is favoureed by strong Nu^(o-) and in the presence of polar aprotic sovlent, optically active halides give. Walden inversion by SN^(2) mechanism. The presence of hetro group (atom) at beta-C atom, unsaturation at beta-C and (-overset(O)overset(||)(C)-) group at alpha-C atomn favor SN^(2) mechanism. Allyl halides and benzyl halides give SN^(1) and SN^(2) reactions. Allyl halides alos give SN^(2) mechanism EDG at ortho- and para- postions in benzyl halides favors SN^(1) mechanism, wheras EWG favors SN^(2) mechanism. Which of the following will gives SN^(2) mechanism gt

    SN^(2) reaction is a bimolecular reaction which takes places by the formation of T.S. Veolcity of the reaction depends on the concentration of the substrate as well as the nucleophile. The reaction is favoureed by strong Nu^(o-) and in the presence of polar aprotic sovlent, optically active halides give. Walken inversion by SN^(2) mechanism. The presence of hero group (atom) at beta-C atom, unsaturation at beta-C and (-overset(O)overset(||)(C)-) group at alpha-C atomn favor SN^(2) mechanism. Allyl halides and benzyl halides give SN^(1) and SN^(2) reactions. Allyl halides alos give SN^(2) mechanism EDG at ortho- and para- postions in benzyl halides favors SN^(1) mechanism, wheras EWG favors SN^(2) mechanism. Which of the following will give SN^(1) reaction?

    In S_(N^1) reactions, primary alkyl halides are more reactive than tertiary alkyl halides.

    Aryl halides are less reactive than alkyl halides towards nuceophilic reagents. Give reasons.

    Which of the following halides are not soluble in water ?

    Aryl halides can be prepared by the action of phosphorus halides on phenols.