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Methanol and ethanol can be distinguishe...

Methanol and ethanol can be distinguished by

A

Lucas test

B

Iodoform test

C

Victor Meyer's test

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To distinguish between methanol and ethanol, we can follow these steps: ### Step 1: Understand the Structure of Methanol and Ethanol - **Methanol (CH3OH)**: It is a primary alcohol with one carbon atom. - **Ethanol (CH3CH2OH)**: It is also a primary alcohol but has two carbon atoms. ### Step 2: Identify the Tests Available The tests mentioned for distinguishing between alcohols are: 1. Lucas Test 2. Iodoform Test 3. Victor-Meyer Test ### Step 3: Analyze the Lucas Test - The Lucas Test is used to differentiate between primary, secondary, and tertiary alcohols. - Since both methanol and ethanol are primary alcohols, they will not show a significant difference in this test. - **Conclusion**: Lucas Test cannot be used to distinguish methanol from ethanol. ### Step 4: Analyze the Iodoform Test - The Iodoform Test is specifically used to identify methyl ketones or alcohols that can be oxidized to methyl ketones. - Ethanol reacts with iodine in the presence of sodium hydroxide to produce a yellow precipitate of iodoform (CHI3). - Methanol does not react in this way and does not produce a precipitate. - **Conclusion**: Iodoform Test can distinguish between methanol and ethanol. ### Step 5: Analyze the Victor-Meyer Test - The Victor-Meyer Test is used to differentiate between primary, secondary, and tertiary alcohols based on the color change observed. - However, it does not specifically distinguish between methanol and ethanol, as both are primary alcohols. - **Conclusion**: Victor-Meyer Test cannot be used to distinguish methanol from ethanol. ### Final Conclusion Based on the analysis of the tests: - **Correct Answer**: Methanol and ethanol can be distinguished by the **Iodoform Test**.
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Knowledge Check

  • Phenol and cyclohexanol can be distinguished by using :

    A
    `FeCl_(3)`
    B
    Na
    C
    `PCl_(3)`
    D
    `CH_(3)COCl`
  • Phenol and benzoic acid can be distinguished by :

    A
    aqueous `NaHCO_(3)`
    B
    aqueous `NaNO_(3)`
    C
    aqueous NaOH
    D
    conc. `H_(2)SO_(4)`
  • 1-propanol and 2-propanol can be best distinguished by :

    A
    oxidation with alkaline `KMnO_(4)` followed by reaction with Fehling's solution
    B
    oxidation with acidic dichromate followed by reaction with Fehling's solution
    C
    oxidation by heating with copper followed by reaction with Fehling's solution
    D
    oxidation with conc. `H_(2)SO_(4)` followed by reaction with Fehling's solution
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