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The shape of BF species is...

The shape of BF species is

A

Tetrahedral

B

Square planar

C

Trigonal planar

D

Linear

Text Solution

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The correct Answer is:
To determine the shape of the BF4- species, we can follow these steps: ### Step 1: Identify the central atom and its valence electrons - The central atom in BF4- is Boron (B). - Boron is in Group 13 of the periodic table and has 3 valence electrons. ### Step 2: Account for the charge of the species - The BF4- species has a -1 charge, which means that Boron has gained an additional electron. - Therefore, Boron effectively has 4 valence electrons (3 from Boron + 1 from the charge). ### Step 3: Determine the number of surrounding atoms - In BF4-, there are 4 Fluorine (F) atoms bonded to the Boron atom. ### Step 4: Calculate the steric number - The steric number is calculated as the sum of the number of sigma bonds and the number of lone pairs on the central atom. - Here, Boron forms 4 sigma bonds with the 4 Fluorine atoms and has no lone pairs. - Thus, the steric number = 4 (4 sigma bonds + 0 lone pairs). ### Step 5: Determine the hybridization - The hybridization can be determined based on the steric number. A steric number of 4 corresponds to sp3 hybridization. ### Step 6: Determine the molecular shape - With sp3 hybridization and a steric number of 4, the molecular shape is tetrahedral. ### Step 7: Determine the bond angles - In a tetrahedral geometry, the bond angles are approximately 109.5 degrees. ### Conclusion - Therefore, the shape of the BF4- species is tetrahedral with bond angles of about 109.5 degrees. ---
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Knowledge Check

  • Describe the shapes of BF_(3) and BH_(4)^(-) . Assign the hybridisation of boron atom in these species.

    A
    `BF_(3)` - Trigonal, `sp^(2)` hybridisation,
    `BH_(4)^(-)` - square planar, `sp^(3)` hybridisation
    B
    `BF_(3)`-Triangle, `sp^(3)` hybridisation,
    `BH_(4)^(-)` - Hexagonal, `sp^(2)` d hybridisation
    C
    `BF_(3)` - Trigonal, `sp^(2)` hybridisation,
    `BH_(4)^(-)` - Tetrahedral, `sp^(3)` hybridisation
    D
    `BF_(3)` - Tetrahedral, `sp^(3)` hybridisation
    `BH_(4)^(-)`- Tetrahedral, `sp^(3)` hybridisation
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