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The oxidation state of Cr in CrO5 is...

The oxidation state of Cr in `CrO_5` is

A

`+4`

B

`+6`

C

`+8`

D

`+10`

Text Solution

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The correct Answer is:
To determine the oxidation state of chromium (Cr) in the compound CrO₅, we can follow these steps: ### Step 1: Understand the structure of CrO₅ CrO₅ is known as chromium oxide peroxide. In this compound, chromium is bonded to one oxygen atom with a double bond and to four oxygen atoms with single bonds, which are part of peroxide groups. ### Step 2: Identify the oxidation states of oxygen In CrO₅: - The oxidation state of the oxygen in the double bond (oxide) is -2. - The oxidation state of the oxygen in the peroxide groups is -1. ### Step 3: Set up the equation for oxidation states Let the oxidation state of chromium be \( x \). The total contribution to the oxidation state from the four peroxide oxygens is: - \( 4 \times (-1) = -4 \) (since there are four peroxide oxygens). The contribution from the one oxide oxygen is: - \( 1 \times (-2) = -2 \). ### Step 4: Write the equation based on the overall charge Since CrO₅ is a neutral compound, the sum of the oxidation states must equal 0. Therefore, we can write the equation: \[ x + (-4) + (-2) = 0 \] ### Step 5: Simplify the equation This simplifies to: \[ x - 4 - 2 = 0 \] \[ x - 6 = 0 \] ### Step 6: Solve for \( x \) Adding 6 to both sides gives: \[ x = +6 \] ### Conclusion The oxidation state of chromium in CrO₅ is +6. ---
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Knowledge Check

  • The oxidation state of Cr in [Cr(NH_(3))_(4)Cl_(2)]^(+) is

    A
    0
    B
    `+1`
    C
    `+2`
    D
    `+3`
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