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Which of the following statements in rel...

Which of the following statements in relation to the hydrogen atom is correct? `3s` orbital is lower in energy than `3p` orbital, `3p` orbital is lower in energy than `3d` orbital, `3s` and `3p` orbitals are lower in energy than `3d` orbital, `3s` and `3p` orbital all have the same energy

A

3 s orbital is lower in energy than '3 p' orbital

B

3 p' orbital is lower in energy than '3 d' orbital

C

3 s' and '3 p' orbitals are lower in energy than '3 d' orbital

D

3 s' and '3 p' orbitals all have the same energy

Text Solution

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The correct Answer is:
A
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Assertion : The 1^(st) IP of Be is greater than that of B Reason : 2p orbital is lower in energy than 2s

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Knowledge Check

  • Which of the following order of energies of molecular orbitals of N_2 is correct?

    A
    `E (pi 2p_x) = E (pi 2p_y) lt E (sigma2 p)lt E (pi^(**) 2p_x) = E (pi^(**)2p_x) = E (pi^(**) 2p_y)`
    B
    `E (pi 2p_x) = E (pi 2p_y) gt E(sigma 2p) gt E (pi^(**) 2p_x) = E (pi^(**) 2p_y)`
    C
    `E(pi2p_x) = E (pi2p_y) lt E (sigma 2p) gt E (pi^(**) 2p_x) = E (pi^(**) 2p_y)`
    D
    `E (pi2p_x) = E (pi 2p_y) gt E (sigma 2p) lt E (pi^(**) 2p_x) = E (pi^(**)2p_y)`
  • Which of the following order of energies of molecular orbitals of N_2 is correct?

    A
    `E(pi 2p_x)=E(pi 2p_y) lt E(sigma 2p_z) lt E(pi^("*") 2p_x)=E(pi^("*")2p_y)`
    B
    `E(pi 2p_x)=E(pi 2p_y) gt E(sigma 2p_z) gt E(pi^("*") 2p_x)=E(pi^("*")2p_y)`
    C
    `E(pi 2p_x)=E(pi 2p_y) lt E(sigma 2p_z) gt E(pi^("*") 2p_x)=E(pi^("*")2p_y)`
    D
    `E(pi 2p_x)=E(pi 2p_y) gt E(sigma 2p_z) lt E(pi^("*") 2p_x)=E(pi^("*")2p_y)`
  • Assertion: The first ionization energy of Be is greater than that of B. Reason : 2p orbital is lower in energy than 2s.

    A
    If both (A) and (R) are correct, but (R) is not the correct explanation of (A).
    B
    If both (A) and (R) are correct, but (R) is not the correct explanation of (A)
    C
    If (A) is correct, but (R) is incorrect.
    D
    If both (A) and (R) are incorrect.
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