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Convert i. 3-Methylaniline into 3 - nitr...

Convert i. 3-Methylaniline into 3 - nitrotoluene ii. Aniline into 1,3,5 -tribromobenzene.

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Convert: 3-Methylaniline into 3-nitrotoluene

Convert:Aniline into 1,3,5-tribromobenzene

Knowledge Check

  • All aliphatic amines are more basic than ammonia but due to delocalization of lone pair of electrons of the nitrogen atom on the benzene ring, aniline is a weaker base than ammonia. The basic strength of the substituted anilines, however, depends upon the nature of the substituent. Whereas electron-donating groups tend to increase, electron-withdrawing groups tend to decrease the basic strength. The base strengthening effect of the electron-donating groups and base weakening effect of the electron-withdrawing groups is, however ,more pronounced at p-than at m-position. However, due to ortho effect, o-substituted anilines are weaker bases than anilines regardless of the nature of substituent whether electron-donating or electron-withdrawing. What is the order of basicity of I. p-methylaniline II. m-methylaniline III, aniline IV. o-methylaniline

    A
    `I gt II gt III gt IV`
    B
    `I gt II gt IV gt III`
    C
    `IV gt I gt II gt III`
    D
    `II gt I gt IV gt III`

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