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Convert i. 3-Methylaniline into 3 - nitr...

Convert i. 3-Methylaniline into 3 - nitrotoluene ii. Aniline into 1,3,5 -tribromobenzene.

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Give one chemical test to distinguish between the following pairs of compounds i. Methylamine and dimethyl amine ii. Secondary and tertiary AMINES iii. Ethylamine and aniline iv. Aniline and benzylamine v. Aniline and N- methyl aniline

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All aliphatic amines are more basic than ammonia but due to delocalization of lone pair of electrons of the nitrogen atom on the benzene ring, aniline is a weaker base than ammonia. The basic strength of the substituted anilines, however, depends upon the nature of the substituent. Whereas electron-donating groups tend to increase, electron-withdrawing groups tend to decrease the basic strength. The base strengthening effect of the electron-donating groups and base weakening effect of the electron-withdrawing groups is, however ,more pronounced at p-than at m-position. However, due to ortho effect, o-substituted anilines are weaker bases than anilines regardless of the nature of substituent whether electron-donating or electron-withdrawing. What is the order of basicity of I. p-methylaniline II. m-methylaniline III, aniline IV. o-methylaniline

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V PUBLICATION-AMINES-QUESTION BANK
  1. Write chemical reaction of aniline with benzoyl chloride and write the...

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  2. Write structures of different isomers corresponding to the molecular f...

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  3. Convert i. 3-Methylaniline into 3 - nitrotoluene ii. Aniline into 1,3,...

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  4. Write IUPAC names of the following compounds and classify them into pr...

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  5. Give one chemical test to distinguish between the following pairs of c...

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  6. Account for the following: i. pKb of -aniline is more than that of met...

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  7. Arrange the following: i) In.decreasing order of the 'pK', values, 'C2...

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  8. How will you convert : i. Ethanoic acid into methanamine ii. Hexaneni...

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  9. Describe a method for the identification of primary, secondary and ter...

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  10. Write short notes on the following: i)Carbylamine reaction ii) Diazoti...

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  11. Accomplish the following conversions: i) Nitrobenzene to benzoic acid.

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  12. An aromatic compound on treatment with aqueous ammonia and heating fo...

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  13. Give plausible explanation for each of the following : i) Why are AMIN...

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  14. Give the structures of A,B and C in the following reactions: CH 3 ​ ...

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  15. Complete the following'reactions: i). C6 H5 NH2+CHCl3+alc KOH rarr ii...

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  16. Why cannot aromtic primary AMINES be prepared by gabrile phthalimide s...

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  17. Write the reactions of (i) aromatic and (ii) aliphatic primary AMINES ...

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  18. (i) How will you convert an alkyl halide into a primary amine having o...

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  19. Can yousuggest a method for the conversion of aniline to phenol? Write...

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  20. Alcoholic AgCN, CH3CI, alc.KCN and LiAlH4 are good friends.One day CH3...

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