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Copper (I) ions are not known in aqueous...

Copper (I) ions are not known in aqueous solution.

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**Step-by-Step Solution:** 1. **Understanding the Cuprous Ion (Cu⁺):** - The cuprous ion (Cu⁺) is the +1 oxidation state of copper. It is important to understand its behavior in aqueous solutions. 2. **Disproportionation Reaction:** - In aqueous solutions, the cuprous ion tends to undergo a disproportionation reaction. This means that Cu⁺ ions can simultaneously oxidize and reduce themselves, leading to the formation of two different products. - The reaction can be represented as: \[ 2 \text{Cu}^+ \rightarrow \text{Cu}^{2+} + \text{Cu} \] - Here, one Cu⁺ ion is oxidized to Cu²⁺, and another Cu⁺ ion is reduced to solid copper (Cu). 3. **Stability of Cupric Ion (Cu²⁺):** - The cupric ion (Cu²⁺) is more stable in aqueous solution compared to the cuprous ion. This stability can be attributed to the hydration energy associated with Cu²⁺ ions. 4. **Hydration Energy Comparison:** - Hydration energy is the energy released when ions are surrounded by water molecules. The hydration energy of Cu²⁺ is greater than that of Cu⁺. - This greater hydration energy compensates for the energy required to remove an additional electron from the copper atom (the second ionization enthalpy). 5. **Conclusion:** - Due to the disproportionation reaction and the greater stability of the cupric ion (Cu²⁺) facilitated by its higher hydration energy, cuprous ions (Cu⁺) are not stable and thus not commonly found in aqueous solutions.
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RESONANCE ENGLISH-D BLOCK ELEMENTS-EXERCISE-2 PART-I
  1. Why is the E^(ϴ) value for the Mn^(3+)//Mn^(2+) couple much more posit...

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  2. Which is a stronger reducing agent Cr^(2+)or Fe^(2+) and why ?

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  3. Explain why Cu^(+) ion is not stable in aqueous solutions?

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  4. The aqueous solution of FeCl(3) is acidic . Why?

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  5. Ferric iodide is very unstable but ferric chloride is not

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  6. Copper dissolves in dilute nitric acid but not in dilute HCl. Why?

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  7. Blue colour of CuSO(4) solution is discharge slowly when an iron rod i...

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  8. Copper (I) ions are not known in aqueous solution.

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  9. Calculate the number of unpaired electrons in the following gaseous io...

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  10. Mercurous ion is written as Hg(2)^(2+) whereas cuprous ion is written ...

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  11. Copper sulphate dissolves in NH(4)OH solution but FeSO(4) does not.

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  12. An aqueous solution of inorganic compounds (X) gives following reactio...

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  13. H(2)S gas is passed through an acidic solution of K(2)Cr(2)O(7) .The s...

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  14. What happen when(i) a small amount of KMnO(4) is added to concentrated...

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  15. A hydrated mettalic salt(A). Light green in colour , on careful heatin...

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  16. A white substance (A) reacts with dilute H(2)SO(4) to produce a colour...

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  17. Write the balanced chemical equation for the following reaction:- Nitr...

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  18. Complete and balance the following equation: Ag(2)S+CuCl(2)+Hg....…....

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  19. Which out of the two ,La(OH)(3) and Lu(OH)(3), is more basic and why?

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  20. One among the lanthanoides, Ce(III), can be easily oxidized to Ce(IV) ...

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