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HCN and HNC molcules are formed by the s...

`HCN` and `HNC` molcules are formed by the same atoms.
Which of the following properties are identical for `HCN` abd `HNC` molecules ?

A

The number of `sigma` bonds.

B

The number of `pi` bonds.

C

The number of lone pairs.

D

Formal charge on `H` atom.

Text Solution

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The correct Answer is:
To determine which properties are identical for the molecules HCN (Hydrogen Cyanide) and HNC (Hydrogen Isocyanide), we will analyze their structures and properties step by step. ### Step 1: Draw the Structures of HCN and HNC - **HCN Structure**: H-C≡N - In HCN, the carbon (C) is triple-bonded to nitrogen (N) and single-bonded to hydrogen (H). - **HNC Structure**: H-N≡C - In HNC, the nitrogen (N) is triple-bonded to carbon (C) and single-bonded to hydrogen (H). ### Step 2: Analyze the Number of Sigma Bonds - **HCN**: - There is 1 sigma bond between H and C, and 1 sigma bond between C and N (the triple bond consists of 1 sigma and 2 pi bonds). - Total sigma bonds = 2. - **HNC**: - There is 1 sigma bond between H and N, and 1 sigma bond between N and C (the triple bond consists of 1 sigma and 2 pi bonds). - Total sigma bonds = 2. **Conclusion**: The number of sigma bonds in both HCN and HNC is identical (2). ### Step 3: Analyze the Number of Pi Bonds - **HCN**: - The triple bond between C and N consists of 2 pi bonds. - **HNC**: - The triple bond between N and C also consists of 2 pi bonds. **Conclusion**: The number of pi bonds in both HCN and HNC is identical (2). ### Step 4: Analyze the Number of Lone Pairs - **HCN**: - The nitrogen atom has 1 lone pair (since it is bonded to one carbon and has a triple bond). - **HNC**: - The nitrogen atom has 1 lone pair, and the carbon atom carries a negative charge which can be considered as a lone pair of electrons. **Conclusion**: The number of lone pairs in both HCN and HNC is identical (1 lone pair on nitrogen). ### Step 5: Analyze the Formal Charges - **HCN**: - Formal charge on H = 0, on C = 0, on N = 0. - **HNC**: - Formal charge on H = 0, on N = +1, on C = -1. **Conclusion**: The formal charges are not identical, as HNC has a formal charge distribution that differs from HCN. ### Final Conclusion The properties that are identical for HCN and HNC are: 1. Number of sigma bonds: 2 (identical) 2. Number of pi bonds: 2 (identical) 3. Number of lone pairs: 1 (identical) However, the formal charges are not identical. ### Summary of Identical Properties - Number of Sigma Bonds: Identical - Number of Pi Bonds: Identical - Number of Lone Pairs: Identical

To determine which properties are identical for the molecules HCN (Hydrogen Cyanide) and HNC (Hydrogen Isocyanide), we will analyze their structures and properties step by step. ### Step 1: Draw the Structures of HCN and HNC - **HCN Structure**: H-C≡N - In HCN, the carbon (C) is triple-bonded to nitrogen (N) and single-bonded to hydrogen (H). - **HNC Structure**: H-N≡C - In HNC, the nitrogen (N) is triple-bonded to carbon (C) and single-bonded to hydrogen (H). ...
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