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What is mutarotation ?...

What is mutarotation ?

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### Step-by-Step Solution: 1. **Definition of Mutarotation**: Mutarotation is defined as the change in the specific rotation of an optically active compound when it is dissolved in a solution over time. This phenomenon occurs due to the interconversion of different anomeric forms of the compound. 2. **Optically Active Compounds**: Optically active compounds are substances that can rotate plane-polarized light. This property is crucial for understanding mutarotation, as the specific rotation changes during the process. 3. **Example of Reducing Sugars**: A common example of mutarotation is observed in reducing sugars, such as glucose. When glucose is dissolved in water, it exhibits mutarotation. 4. **Equilibrium of Forms**: In an aqueous solution, glucose exists in three forms: - Alpha-D-glucose - Beta-D-glucose - Open-chain form 5. **Proportions of Forms**: The equilibrium between these forms results in specific proportions: - Beta-D-glucose: 64% - Alpha-D-glucose: 36% - Open-chain form: 0.02% (negligible) 6. **Conclusion**: The change in the specific rotation of glucose over time, as it equilibrates between these forms, is what we refer to as mutarotation.

### Step-by-Step Solution: 1. **Definition of Mutarotation**: Mutarotation is defined as the change in the specific rotation of an optically active compound when it is dissolved in a solution over time. This phenomenon occurs due to the interconversion of different anomeric forms of the compound. 2. **Optically Active Compounds**: Optically active compounds are substances that can rotate plane-polarized light. This property is crucial for understanding mutarotation, as the specific rotation changes during the process. ...
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