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Statement-1 : Gly-Ala is a structural is...

Statement-1 : Gly-Ala is a structural isomer pf Ala-Gly.
Statement-2 : In Al-Gly, Alanine is the `N`-terminal amino acid.

A

STATEMENT-1 is true, STATEMENT-2 is true and STATEMENT-2 is
correct explanation for STATEMENT-1

B

STATEMENT-1 is true, STATEMENT-2 is true and STATEMENT-2 is not correct explanation for STATEMENT-1

C

STATEMENT-1 is true, STATEMENT-2 is false

D

STATEMENT-1 is false, STATEMENT-2 is true

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements provided in the question, we will break down the reasoning step by step. ### Step 1: Understanding the Statements - **Statement 1**: Gly-Ala is a structural isomer of Ala-Gly. - **Statement 2**: In Ala-Gly, Alanine is the N-terminal amino acid. ### Step 2: Identifying the Amino Acids - Glycine (Gly) has the structure: H2N-CH2-COOH - Alanine (Ala) has the structure: H2N-CH(CH3)-COOH ### Step 3: Formation of Peptides - **Gly-Ala**: When glycine and alanine are combined, the peptide bond forms between the amino group of glycine and the carboxyl group of alanine, resulting in: - Structure: H2N-CH2-CO-NH-CH(CH3)-COOH - Here, glycine is at the N-terminal and alanine is at the C-terminal. - **Ala-Gly**: When alanine and glycine are combined, the peptide bond forms between the amino group of alanine and the carboxyl group of glycine, resulting in: - Structure: H2N-CH(CH3)-CO-NH-CH2-COOH - Here, alanine is at the N-terminal and glycine is at the C-terminal. ### Step 4: Identifying N-terminal and C-terminal - **N-terminal**: The amino acid with a free amino group (NH2) at one end of the peptide. - **C-terminal**: The amino acid with a free carboxyl group (COOH) at the other end of the peptide. In **Ala-Gly**, alanine is indeed the N-terminal amino acid, confirming Statement 2 is correct. ### Step 5: Checking for Structural Isomerism - Structural isomers have the same molecular formula but different structures. - Both Gly-Ala and Ala-Gly have the same molecular formula: - Total Carbons (C): 5 - Total Hydrogens (H): 10 - Total Nitrogens (N): 2 Since they differ in structure (the order of amino acids is different), they are indeed structural isomers, confirming Statement 1 is also correct. ### Conclusion - **Statement 1**: True (Gly-Ala is a structural isomer of Ala-Gly) - **Statement 2**: True (In Ala-Gly, alanine is the N-terminal amino acid) - However, Statement 2 does not explain Statement 1. ### Final Answer - Statement 1 is true. - Statement 2 is true. - Statement 2 is not the correct explanation for Statement 1.

To analyze the statements provided in the question, we will break down the reasoning step by step. ### Step 1: Understanding the Statements - **Statement 1**: Gly-Ala is a structural isomer of Ala-Gly. - **Statement 2**: In Ala-Gly, Alanine is the N-terminal amino acid. ### Step 2: Identifying the Amino Acids - Glycine (Gly) has the structure: H2N-CH2-COOH ...
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