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The rate constant of the reaction A rarr...

The rate constant of the reaction `A rarr 2B` is `1.0 xx 10^(-3)` mol `"lit" ^(-1)" min"^(-1)`, if the initial concentration of A is `1.0` mole `lit^(-1)` . What would be the concentration of B after 100 minutes.

A

`0.1" mol lit"^(-1)`

B

`0.2 "mol lit"^(-1)`

C

`0.9" mol lit"^(-1)`

D

`1.8 "mol lit"^(-1)`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the concentration of B after 100 minutes for the reaction \( A \rightarrow 2B \) given the rate constant and initial concentration of A. ### Step-by-Step Solution: 1. **Identify the Given Data:** - Rate constant \( k = 1.0 \times 10^{-3} \, \text{mol L}^{-1} \text{min}^{-1} \) - Initial concentration of A, \( [A]_0 = 1.0 \, \text{mol L}^{-1} \) - Time, \( t = 100 \, \text{minutes} \) 2. **Calculate the Amount of A Reacted:** The amount of A that reacts can be calculated using the formula: \[ \text{Reactant used} = k \times t \] Substituting the values: \[ \text{Reactant used} = (1.0 \times 10^{-3} \, \text{mol L}^{-1} \text{min}^{-1}) \times (100 \, \text{min}) = 0.1 \, \text{mol L}^{-1} \] 3. **Determine the Remaining Concentration of A:** The concentration of A after 100 minutes can be calculated as: \[ [A] = [A]_0 - \text{Reactant used} \] Substituting the values: \[ [A] = 1.0 \, \text{mol L}^{-1} - 0.1 \, \text{mol L}^{-1} = 0.9 \, \text{mol L}^{-1} \] 4. **Calculate the Concentration of B Formed:** From the stoichiometry of the reaction \( A \rightarrow 2B \), for every 1 mole of A that reacts, 2 moles of B are produced. Therefore, the concentration of B formed can be calculated as: \[ [B] = 2 \times \text{Reactant used} \] Substituting the values: \[ [B] = 2 \times 0.1 \, \text{mol L}^{-1} = 0.2 \, \text{mol L}^{-1} \] 5. **Final Answer:** The concentration of B after 100 minutes is: \[ [B] = 0.2 \, \text{mol L}^{-1} \]

To solve the problem, we need to determine the concentration of B after 100 minutes for the reaction \( A \rightarrow 2B \) given the rate constant and initial concentration of A. ### Step-by-Step Solution: 1. **Identify the Given Data:** - Rate constant \( k = 1.0 \times 10^{-3} \, \text{mol L}^{-1} \text{min}^{-1} \) - Initial concentration of A, \( [A]_0 = 1.0 \, \text{mol L}^{-1} \) - Time, \( t = 100 \, \text{minutes} \) ...
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