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{:("Column-I","Column-II"),((A)XeF4,(p)s...

`{:("Column-I","Column-II"),((A)XeF_4,(p)sp^3d "see-saw geometry"),((B)SF_4,(q)sp^3d^2 "square planar"),((C )SF_6, (r)sp^3d^3 "distorted octahedral geometry"),((D)XeF_6,(s)sp^3d^2 "octahedral geometry"):}`

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To solve the given question, we need to determine the hybridization and geometry of the compounds listed in Column-I and match them with the options in Column-II. Let's go through each compound step by step. ### Step 1: Determine the hybridization and geometry of XeF₄ 1. **Valence Electrons**: Xenon (Xe) has 8 valence electrons, and each fluorine (F) contributes 1 electron. Since there are 4 fluorine atoms, the total is: \[ 8 + (4 \times 1) = 12 \text{ electrons} \] 2. **Hybridization Calculation**: The formula for hybridization is: \[ \text{Hybridization} = \frac{\text{Valence Electrons} + \text{Monovalent Atoms} + \text{Negative Charges} - \text{Positive Charges}}{2} \] Here, there are no charges, so: \[ \text{Hybridization} = \frac{12}{2} = 6 \quad (\text{sp}^3d^2) \] 3. **Geometry**: With 4 bond pairs and 2 lone pairs, XeF₄ has a square planar geometry. ### Step 2: Determine the hybridization and geometry of SF₄ 1. **Valence Electrons**: Sulfur (S) has 6 valence electrons, and there are 4 fluorine atoms: \[ 6 + (4 \times 1) = 10 \text{ electrons} \] 2. **Hybridization Calculation**: \[ \text{Hybridization} = \frac{10}{2} = 5 \quad (\text{sp}^3d) \] 3. **Geometry**: With 4 bond pairs and 1 lone pair, SF₄ has a seesaw geometry. ### Step 3: Determine the hybridization and geometry of SF₆ 1. **Valence Electrons**: Sulfur (S) has 6 valence electrons, and there are 6 fluorine atoms: \[ 6 + (6 \times 1) = 12 \text{ electrons} \] 2. **Hybridization Calculation**: \[ \text{Hybridization} = \frac{12}{2} = 6 \quad (\text{sp}^3d^2) \] 3. **Geometry**: With 6 bond pairs and 0 lone pairs, SF₆ has an octahedral geometry. ### Step 4: Determine the hybridization and geometry of XeF₆ 1. **Valence Electrons**: Xenon (Xe) has 8 valence electrons, and there are 6 fluorine atoms: \[ 8 + (6 \times 1) = 14 \text{ electrons} \] 2. **Hybridization Calculation**: \[ \text{Hybridization} = \frac{14}{2} = 7 \quad (\text{sp}^3d^3) \] 3. **Geometry**: With 6 bond pairs and 1 lone pair, XeF₆ has a distorted octahedral geometry. ### Summary of Results - **XeF₄**: Hybridization = sp³d², Geometry = Square Planar (matches with q) - **SF₄**: Hybridization = sp³d, Geometry = Seesaw (matches with p) - **SF₆**: Hybridization = sp³d², Geometry = Octahedral (matches with s) - **XeF₆**: Hybridization = sp³d³, Geometry = Distorted Octahedral (matches with r) ### Final Matching - A → q (XeF₄) - B → p (SF₄) - C → s (SF₆) - D → r (XeF₆)

To solve the given question, we need to determine the hybridization and geometry of the compounds listed in Column-I and match them with the options in Column-II. Let's go through each compound step by step. ### Step 1: Determine the hybridization and geometry of XeF₄ 1. **Valence Electrons**: Xenon (Xe) has 8 valence electrons, and each fluorine (F) contributes 1 electron. Since there are 4 fluorine atoms, the total is: \[ 8 + (4 \times 1) = 12 \text{ electrons} \] 2. **Hybridization Calculation**: The formula for hybridization is: ...
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Match the compounds listed in column I with characteristic listed in column II. {:("Column-I","Column-II"),((A)SF_2,(p)sp^3"and bent"),((B)KrF_4,(q)"Lone pair"),((C )NOCl,(r)"Bond angle less than"109^@28'),((D )N(Me)_3,(s)sp^2"and bent"),(,(t)sp^3d^2"and square planar"):}

Knowledge Check

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    A
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    B
    `(A) to (iii), (B) to (i), (C ) to (iv), (D) to (ii)`
    C
    `(A) to (ii), (B) to (iii), (C ) to (i), (D) to (iv) `
    D
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