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In how many of the following complex ion...

In how many of the following complex ions, the central metal ions use (n-1)d, ns and np orbitals for hybridisation ?
`[Mn(CN)_6]^(4-), [Ni(NH_3)_6]^(3-), [Co( o x)_3]^(3-), [Cu(NO_2)_6]^(4-), [AgF_4]^(-)`

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To determine how many of the given complex ions have central metal ions that use (n-1)d, ns, and np orbitals for hybridization, we will analyze each complex ion one by one. ### Step 1: Analyze [Mn(CN)6]^(4-) - **Central Metal Ion**: Manganese (Mn) - **Oxidation State**: In this complex, CN^- is a strong field ligand and does not affect the oxidation state. The oxidation state of Mn can be calculated as follows: - Let the oxidation state of Mn be x. - x + 6(-1) = -4 → x - 6 = -4 → x = +2 - **Electron Configuration**: Mn (Atomic number 25) has the electron configuration [Ar] 3d^5 4s^2. - **Hybridization**: The hybridization involves 3d, 4s, and 4p orbitals. - **Conclusion**: This complex uses (n-1)d, ns, and np orbitals. ### Step 2: Analyze [Ni(NH3)6]^(3-) - **Central Metal Ion**: Nickel (Ni) - **Oxidation State**: For NH3, the oxidation state of Ni can be calculated similarly: - Let the oxidation state of Ni be y. - y + 6(0) = -3 → y = -3 - **Electron Configuration**: Ni (Atomic number 28) has the electron configuration [Ar] 3d^8 4s^2. - **Hybridization**: The hybridization involves 3d, 4s, and 4p orbitals. - **Conclusion**: This complex also uses (n-1)d, ns, and np orbitals. ### Step 3: Analyze [Co(ox)3]^(3-) - **Central Metal Ion**: Cobalt (Co) - **Oxidation State**: For oxalate (ox), which is a bidentate ligand: - Let the oxidation state of Co be z. - z + 3(-2) = -3 → z - 6 = -3 → z = +3 - **Electron Configuration**: Co (Atomic number 27) has the electron configuration [Ar] 3d^7 4s^2. - **Hybridization**: The hybridization involves 3d, 4s, and 4p orbitals. - **Conclusion**: This complex uses (n-1)d, ns, and np orbitals. ### Step 4: Analyze [Cu(NO2)6]^(4-) - **Central Metal Ion**: Copper (Cu) - **Oxidation State**: For NO2, which is a bidentate ligand: - Let the oxidation state of Cu be w. - w + 6(-1) = -4 → w - 6 = -4 → w = +2 - **Electron Configuration**: Cu (Atomic number 29) has the electron configuration [Ar] 3d^10 4s^1. - **Hybridization**: The hybridization involves 3d, 4s, and 4p orbitals. - **Conclusion**: This complex also uses (n-1)d, ns, and np orbitals. ### Step 5: Analyze [AgF4]^(-) - **Central Metal Ion**: Silver (Ag) - **Oxidation State**: For F, which is a monodentate ligand: - Let the oxidation state of Ag be v. - v + 4(-1) = -1 → v - 4 = -1 → v = +3 - **Electron Configuration**: Ag (Atomic number 47) has the electron configuration [Kr] 4d^10 5s^1. - **Hybridization**: The hybridization involves 4d, 5s, and 5p orbitals. - **Conclusion**: This complex does not use (n-1)d, ns, and np orbitals. ### Final Count: - The complexes that use (n-1)d, ns, and np orbitals are: - [Mn(CN)6]^(4-) - [Ni(NH3)6]^(3-) - [Co(ox)3]^(3-) - [Cu(NO2)6]^(4-) Thus, the total number of complexes that use (n-1)d, ns, and np orbitals is **4**. ### Summary of the Answer: The answer is **4**.

To determine how many of the given complex ions have central metal ions that use (n-1)d, ns, and np orbitals for hybridization, we will analyze each complex ion one by one. ### Step 1: Analyze [Mn(CN)6]^(4-) - **Central Metal Ion**: Manganese (Mn) - **Oxidation State**: In this complex, CN^- is a strong field ligand and does not affect the oxidation state. The oxidation state of Mn can be calculated as follows: - Let the oxidation state of Mn be x. - x + 6(-1) = -4 → x - 6 = -4 → x = +2 - **Electron Configuration**: Mn (Atomic number 25) has the electron configuration [Ar] 3d^5 4s^2. ...
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Among the following complex ions, the species whose central metal atom does not have 'd' electron is : [MnO_(4)]^(-) [CO(NH_(3))_(6)]^(3+) [Fe(CN)_(6)]^(3-) [Cr(H_(2)O)_(6)]^(3+)

Which of the following complexes are not correctly matched with the hybridisation of their central metal ion ? (a) [Ni(CO)_4] , sp^(3) (b) [Ni(CN)_4]^(2-) , sp^(3) (c ) [CoF_6]^(3-) , d^(2)sp^(3) (d) [Fe(CN)_6]^(3-) , sp^(3)d^(2) Select the correct option :

Explain the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in the units : [Cr(NH_3)_6]^(3+) , [Ni(CO)_4]

Among the complex ions given below which is/are outer-orbitals complex-I- [Co(CN)_6]^(4-) II- [ Fe(H_2O)_6]^(2+) III- [Fe F_6]^(3-) IV- [CoF_6]^(3-)

Using crystal field theory, draw energy level diagram, write electronic configuration of the central metal atom/ion and determine the magnetic moment value in the following (a) [CoF_(6)]^(3-), [Co(H_(2)O)_(6)]^(2+), [Co(CN)_(6)]^(3-) (b) FeF_(6)^(3-), [Fe(H_(2)O)_(6)]^(2+), [Fe(CN)_(6)]^(4-)

Total number of low spin complexes are [Fe(CN)_6^(3-),[Co(NO_2)_6]^(3-),[FeF_6]^(3-)[IrF_6]^(3-),[Co(NH_3)_6]^(3+),[Co(H_2O)_6]^(+2),[Mn(H_2O)_6]^(3+)

Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units [Co(NH_3)_6]^(3+) , [Cr(NH_3)_6]^(3+),[Ni(CO)_4] [At. Nos. : Co = 27, Cr = 24 , Ni = 28]

Which of the followimg complex compound(s) is/are paramagnetic and low spin? (I) K_(3)[Fe(CN_(6))] (II) [Ni(CO)_(4)]^(0) (III) [Cr(NH_(3))_(6)]^(3+) (IV) [Mn(CN)_(6)]^(4-)

Name of the following complex ions (a) [PdBr_(4)]^(2-) (b) [CuCl_(2)]^(o+) (c ) [Au(CN)_(4)]^(o+)(d) [AlF_(6)]^(3-) [Cr(NH_(3))_(6)]^(3-) (f) [Zn(NH_(3))_(4)]^(2+) (g) [Fe(CN)_(6)]^(3-) .

In [Ni(H_(2)O)_(6)]^(2+) , the hybridisation of central metal ion is :

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