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In how many of the following complex ion...

In how many of the following complex ions, the central metal ions use (n-1)d, ns and np orbitals for hybridisation ?
`[Mn(CN)_6]^(4-), [Ni(NH_3)_6]^(3-), [Co( o x)_3]^(3-), [Cu(NO_2)_6]^(4-), [AgF_4]^(-)`

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To determine how many of the given complex ions have central metal ions that use (n-1)d, ns, and np orbitals for hybridization, we will analyze each complex ion one by one. ### Step 1: Analyze [Mn(CN)6]^(4-) - **Central Metal Ion**: Manganese (Mn) - **Oxidation State**: In this complex, CN^- is a strong field ligand and does not affect the oxidation state. The oxidation state of Mn can be calculated as follows: - Let the oxidation state of Mn be x. - x + 6(-1) = -4 → x - 6 = -4 → x = +2 - **Electron Configuration**: Mn (Atomic number 25) has the electron configuration [Ar] 3d^5 4s^2. - **Hybridization**: The hybridization involves 3d, 4s, and 4p orbitals. - **Conclusion**: This complex uses (n-1)d, ns, and np orbitals. ### Step 2: Analyze [Ni(NH3)6]^(3-) - **Central Metal Ion**: Nickel (Ni) - **Oxidation State**: For NH3, the oxidation state of Ni can be calculated similarly: - Let the oxidation state of Ni be y. - y + 6(0) = -3 → y = -3 - **Electron Configuration**: Ni (Atomic number 28) has the electron configuration [Ar] 3d^8 4s^2. - **Hybridization**: The hybridization involves 3d, 4s, and 4p orbitals. - **Conclusion**: This complex also uses (n-1)d, ns, and np orbitals. ### Step 3: Analyze [Co(ox)3]^(3-) - **Central Metal Ion**: Cobalt (Co) - **Oxidation State**: For oxalate (ox), which is a bidentate ligand: - Let the oxidation state of Co be z. - z + 3(-2) = -3 → z - 6 = -3 → z = +3 - **Electron Configuration**: Co (Atomic number 27) has the electron configuration [Ar] 3d^7 4s^2. - **Hybridization**: The hybridization involves 3d, 4s, and 4p orbitals. - **Conclusion**: This complex uses (n-1)d, ns, and np orbitals. ### Step 4: Analyze [Cu(NO2)6]^(4-) - **Central Metal Ion**: Copper (Cu) - **Oxidation State**: For NO2, which is a bidentate ligand: - Let the oxidation state of Cu be w. - w + 6(-1) = -4 → w - 6 = -4 → w = +2 - **Electron Configuration**: Cu (Atomic number 29) has the electron configuration [Ar] 3d^10 4s^1. - **Hybridization**: The hybridization involves 3d, 4s, and 4p orbitals. - **Conclusion**: This complex also uses (n-1)d, ns, and np orbitals. ### Step 5: Analyze [AgF4]^(-) - **Central Metal Ion**: Silver (Ag) - **Oxidation State**: For F, which is a monodentate ligand: - Let the oxidation state of Ag be v. - v + 4(-1) = -1 → v - 4 = -1 → v = +3 - **Electron Configuration**: Ag (Atomic number 47) has the electron configuration [Kr] 4d^10 5s^1. - **Hybridization**: The hybridization involves 4d, 5s, and 5p orbitals. - **Conclusion**: This complex does not use (n-1)d, ns, and np orbitals. ### Final Count: - The complexes that use (n-1)d, ns, and np orbitals are: - [Mn(CN)6]^(4-) - [Ni(NH3)6]^(3-) - [Co(ox)3]^(3-) - [Cu(NO2)6]^(4-) Thus, the total number of complexes that use (n-1)d, ns, and np orbitals is **4**. ### Summary of the Answer: The answer is **4**.

To determine how many of the given complex ions have central metal ions that use (n-1)d, ns, and np orbitals for hybridization, we will analyze each complex ion one by one. ### Step 1: Analyze [Mn(CN)6]^(4-) - **Central Metal Ion**: Manganese (Mn) - **Oxidation State**: In this complex, CN^- is a strong field ligand and does not affect the oxidation state. The oxidation state of Mn can be calculated as follows: - Let the oxidation state of Mn be x. - x + 6(-1) = -4 → x - 6 = -4 → x = +2 - **Electron Configuration**: Mn (Atomic number 25) has the electron configuration [Ar] 3d^5 4s^2. ...
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  • Among the following complex ions, the species whose central metal atom does not have 'd' electron is : [MnO_(4)]^(-) [CO(NH_(3))_(6)]^(3+) [Fe(CN)_(6)]^(3-) [Cr(H_(2)O)_(6)]^(3+)

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