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Which of the following alcohol will show...

Which of the following alcohol will show positive iodoform test ?

A

methanol

B

Propan 2-ol

C

pentan 3-ol

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine which alcohol will show a positive iodoform test, we need to understand the conditions required for this test. The iodoform test is positive for alcohols that can be oxidized to form a methyl ketone (a ketone with a methyl group adjacent to the carbonyl group). ### Step-by-Step Solution: 1. **Identify the Alcohols**: We need to examine the given alcohols to see if they can be oxidized to form a methyl ketone. The alcohols mentioned are methanol, propane-2-ol, and pentane-3-ol. 2. **Check Methanol**: - Structure: Methanol (CH₃OH). - Analysis: Methanol is a primary alcohol and cannot be oxidized to a ketone. Therefore, it cannot show a positive iodoform test. 3. **Check Propan-2-ol**: - Structure: Propan-2-ol (CH₃CHOHCH₃). - Analysis: When oxidized, propan-2-ol forms acetone (CH₃COCH₃), which is a methyl ketone. Since it has a methyl group adjacent to the carbonyl group, it will show a positive iodoform test. 4. **Check Pentane-3-ol**: - Structure: Pentane-3-ol (CH₃CH₂CHOHCH₂CH₃). - Analysis: Upon oxidation, pentane-3-ol forms a ketone (CH₃CH₂C(=O)CH₂CH₃). This ketone does not have a methyl group adjacent to the carbonyl group, so it will not show a positive iodoform test. 5. **Conclusion**: - Methanol: Negative iodoform test. - Propan-2-ol: Positive iodoform test. - Pentane-3-ol: Negative iodoform test. Thus, the only alcohol that shows a positive iodoform test is **propan-2-ol**. ### Final Answer: **Propan-2-ol (Option 2) will show a positive iodoform test.** ---

To determine which alcohol will show a positive iodoform test, we need to understand the conditions required for this test. The iodoform test is positive for alcohols that can be oxidized to form a methyl ketone (a ketone with a methyl group adjacent to the carbonyl group). ### Step-by-Step Solution: 1. **Identify the Alcohols**: We need to examine the given alcohols to see if they can be oxidized to form a methyl ketone. The alcohols mentioned are methanol, propane-2-ol, and pentane-3-ol. 2. **Check Methanol**: - Structure: Methanol (CH₃OH). ...
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Knowledge Check

  • Which of the following alcohols will show positive iodoform test?

    A
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    B
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