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Ammonium ion is :...

Ammonium ion is :

A

Lewis acid

B

Lewis base

C

Bronsted acid

D

Bronsted base

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The correct Answer is:
To determine the nature of the ammonium ion (NH₄⁺), we can analyze its properties based on the definitions of Lewis acids and bases, as well as Brønsted acids and bases. Here is a step-by-step solution: ### Step 1: Identify the structure of the ammonium ion The ammonium ion (NH₄⁺) consists of one nitrogen atom bonded to four hydrogen atoms. The nitrogen atom has an atomic number of 7, with an electronic configuration of 1s² 2s² 2p³. When it forms the ammonium ion, it loses one electron, resulting in a configuration of 1s² 2s² 2p². **Hint:** Remember that the ammonium ion is formed by the addition of a proton (H⁺) to ammonia (NH₃). ### Step 2: Analyze the Lewis acid-base theory - **Lewis Acid:** A Lewis acid is defined as a species that can accept a pair of electrons. - **Lewis Base:** A Lewis base is defined as a species that can donate a pair of electrons. In the case of NH₄⁺, nitrogen has no vacant orbitals available to accept electrons since its octet is complete. Therefore, it cannot act as a Lewis acid. Additionally, NH₄⁺ does not have a lone pair of electrons to donate, so it cannot act as a Lewis base either. **Hint:** Check the electron configuration and bonding to determine if there are available electrons for donation or acceptance. ### Step 3: Analyze the Brønsted acid-base theory - **Brønsted Acid:** A Brønsted acid is a species that can donate a proton (H⁺). - **Brønsted Base:** A Brønsted base is a species that can accept a proton (H⁺). The ammonium ion (NH₄⁺) can donate a proton to form ammonia (NH₃) and a hydrogen ion (H⁺). Therefore, NH₄⁺ acts as a Brønsted acid. **Hint:** Consider the ability of a species to donate or accept protons to classify it as a Brønsted acid or base. ### Step 4: Conclusion Based on the analysis: - NH₄⁺ does not act as a Lewis acid or base. - NH₄⁺ acts as a Brønsted acid because it can donate a proton. Thus, the correct classification of the ammonium ion is that it is a **Brønsted acid**. **Final Answer:** Ammonium ion (NH₄⁺) is a Brønsted acid.

To determine the nature of the ammonium ion (NH₄⁺), we can analyze its properties based on the definitions of Lewis acids and bases, as well as Brønsted acids and bases. Here is a step-by-step solution: ### Step 1: Identify the structure of the ammonium ion The ammonium ion (NH₄⁺) consists of one nitrogen atom bonded to four hydrogen atoms. The nitrogen atom has an atomic number of 7, with an electronic configuration of 1s² 2s² 2p³. When it forms the ammonium ion, it loses one electron, resulting in a configuration of 1s² 2s² 2p². **Hint:** Remember that the ammonium ion is formed by the addition of a proton (H⁺) to ammonia (NH₃). ### Step 2: Analyze the Lewis acid-base theory ...
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Knowledge Check

  • Assertion :- A solution of NH_(4)Cl in water is acidic in nature. Reacon : - Ammonium ions undergo hydroysis to from NH_(4)OH .

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
  • Ammonia acts as a very good ligand but ammonium ion does not form complexes because

    A
    `NH_(3)` is a gas while `NH_(4)^(+)` is in liquid form
    B
    `NH_(3)` undergoes `sp^(3)` hybridisation while `NH_(4)^(+)` undergoes `sp^3` d hybridisation
    C
    `NH_(4)^(+)` ion does not have any lone pair of electrons
    D
    `NH_(4)^+` ion has one unpaired electron while `NH_(3)` has two unpaired electrons .
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    Draw the electron dot structure of : [i] Nitrogen molecule [N = 7] , [ii] Sodium chloride [Na = 11, Cl = 17] , [iii] Ammonium ion [N = 7, H = 1 ]

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