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Give an example of oxidation of halide b...

Give an example of oxidation of halide by another halogen. Explain the feasibility of the reaction.

Text Solution

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The correct Answer is:
`2KI(aq.)+Cl_(2) to 2KCl(aq.) + I_(2)`
In the reaction `Cl_(2)` oxidises iodide ion (-1 oxidation state) to `I_(2)` (0 oxidation state).`Cl_(2)` has higher oxidation potential than `I_(2)` and thus oxidises iodide to iodine getting itself reduced to chloride ion. Similarly,
`({:(2l^(-),(aq.),to,I_(2)(s),+,2e^(-)),(Cl_(2),(g),+,2e^(-),to,2Cl^(-),(aq.)):})/(2I^(-)(aq)+Cl_(2)(g)toI_(2)(s)+2Cl^(-)(aq.))`
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Knowledge Check

  • An example of halide ore is

    A
    Cassiterite
    B
    Anglesite
    C
    Siderite
    D
    Carnallite
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