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The energy of stable states of the hydro...

The energy of stable states of the hydrogen atom is given by `E_(n)=-2.18xx10^(-8)//n^(2)[J]` where n denotes the principal quantum number.
Calculate the energy differences between `n=2` (first excited state) and `n=1` (ground state) and between `n=7` and `n=1`.

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To solve the problem, we will calculate the energy differences between the specified states of the hydrogen atom using the given formula for energy levels. ### Step 1: Write down the energy formula The energy of stable states of the hydrogen atom is given by: \[ E_n = -\frac{2.18 \times 10^{-8}}{n^2} \, \text{J} \] ### Step 2: Calculate the energy for \( n = 1 \) (ground state) Substituting \( n = 1 \) into the formula: \[ E_1 = -\frac{2.18 \times 10^{-8}}{1^2} = -2.18 \times 10^{-8} \, \text{J} \] ### Step 3: Calculate the energy for \( n = 2 \) (first excited state) Substituting \( n = 2 \) into the formula: \[ E_2 = -\frac{2.18 \times 10^{-8}}{2^2} = -\frac{2.18 \times 10^{-8}}{4} = -5.45 \times 10^{-9} \, \text{J} \] ### Step 4: Calculate the energy difference between \( n = 2 \) and \( n = 1 \) The energy difference \( \Delta E_{2 \to 1} \) is given by: \[ \Delta E_{2 \to 1} = E_1 - E_2 \] Substituting the values: \[ \Delta E_{2 \to 1} = (-2.18 \times 10^{-8}) - (-5.45 \times 10^{-9}) \] \[ = -2.18 \times 10^{-8} + 5.45 \times 10^{-9} \] \[ = -1.635 \times 10^{-8} \, \text{J} \] ### Step 5: Calculate the energy for \( n = 7 \) Substituting \( n = 7 \) into the formula: \[ E_7 = -\frac{2.18 \times 10^{-8}}{7^2} = -\frac{2.18 \times 10^{-8}}{49} = -4.45 \times 10^{-10} \, \text{J} \] ### Step 6: Calculate the energy difference between \( n = 7 \) and \( n = 1 \) The energy difference \( \Delta E_{7 \to 1} \) is given by: \[ \Delta E_{7 \to 1} = E_1 - E_7 \] Substituting the values: \[ \Delta E_{7 \to 1} = (-2.18 \times 10^{-8}) - (-4.45 \times 10^{-10}) \] \[ = -2.18 \times 10^{-8} + 4.45 \times 10^{-10} \] \[ = -2.1355 \times 10^{-8} \, \text{J} \] ### Final Answers 1. The energy difference between \( n = 2 \) and \( n = 1 \) is: \[ \Delta E_{2 \to 1} = 1.635 \times 10^{-8} \, \text{J} \] 2. The energy difference between \( n = 7 \) and \( n = 1 \) is: \[ \Delta E_{7 \to 1} = 2.1355 \times 10^{-8} \, \text{J} \]
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Knowledge Check

  • The Bohr's energy of a stationary state of hydrogen atom is given as E_(n)=(-2pi^(2)me^(4))/(n^(2)h^(2)) . Putting the values of m and e for n^(th) energy level which is not the correct value?

    A
    `E_(n)=(-21.8xx10^(-19))/(n^(2))J atom^(-1)`
    B
    `E_(n)=(-13.6)/(n^(2))eV atom^(-1)`
    C
    `E_(n)=(-1312)/(n^(2))kJ mol^(-1)`
    D
    `E_(n)=(-12.8xx10^(-19))/(n^(2))erg atom^(-1)`
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