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The energy of stable states of the hydro...

The energy of stable states of the hydrogen atom is given by `E_(n)=-2.18xx10^(-8)//n^(2)[J]` where n denotes the principal quantum number.
In what spectral range is the Lyman series lying?

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To determine the spectral range of the Lyman series for the hydrogen atom, we will follow these steps: ### Step 1: Understand the Lyman Series The Lyman series corresponds to electronic transitions in a hydrogen atom where the electron falls to the n=1 energy level (ground state). The transitions can occur from higher energy levels (n=2, n=3, n=4, etc.) down to n=1. ### Step 2: Calculate the Energy Levels The energy of the stable states of the hydrogen atom is given by the formula: \[ E_n = -\frac{2.18 \times 10^{-8}}{n^2} \text{ J} \] We need to calculate the energy for n=1 (ground state) and for n approaching infinity (ionization). - For n=1: \[ E_1 = -\frac{2.18 \times 10^{-8}}{1^2} = -2.18 \times 10^{-8} \text{ J} \] - For n approaching infinity (ionization): \[ E_{\infty} = -\frac{2.18 \times 10^{-8}}{\infty^2} = 0 \text{ J} \] ### Step 3: Calculate the Energy Difference The energy difference (ΔE) for a transition from n to n=1 is: \[ \Delta E = E_1 - E_n \] For n=2: \[ E_2 = -\frac{2.18 \times 10^{-8}}{2^2} = -\frac{2.18 \times 10^{-8}}{4} = -5.45 \times 10^{-9} \text{ J} \] So, \[ \Delta E = (-2.18 \times 10^{-8}) - (-5.45 \times 10^{-9}) = -1.635 \times 10^{-18} \text{ J} \] For n=3: \[ E_3 = -\frac{2.18 \times 10^{-8}}{3^2} = -\frac{2.18 \times 10^{-8}}{9} = -2.42 \times 10^{-9} \text{ J} \] So, \[ \Delta E = (-2.18 \times 10^{-8}) - (-2.42 \times 10^{-9}) = -1.936 \times 10^{-18} \text{ J} \] ### Step 4: Convert Energy to Wavelength Using the formula: \[ E = \frac{hc}{\lambda} \] Where: - \( h = 6.626 \times 10^{-34} \text{ J s} \) (Planck's constant) - \( c = 3 \times 10^8 \text{ m/s} \) (speed of light) Rearranging gives: \[ \lambda = \frac{hc}{E} \] Calculating for the energy difference calculated for n=2: \[ \lambda = \frac{(6.626 \times 10^{-34})(3 \times 10^8)}{1.635 \times 10^{-18}} \approx 1.215 \times 10^{-7} \text{ m} = 121.5 \text{ nm} \] ### Step 5: Determine the Spectral Range The Lyman series transitions from n=2 to n=1 gives us a wavelength of approximately 121.5 nm, which falls in the ultraviolet (UV) region of the electromagnetic spectrum. ### Conclusion The spectral range of the Lyman series lies in the UV region. ---
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The energy of stable states of the hydrogen atom is given by E_(n)=-2.18xx10^(-8)//n^(2)[J] where n denotes the principal quantum number. Can a single photon, emitted in the first and//or sixth line of the Lyman series, ionize: {:a) another hydrogen atom in its ground state? {:b) a copper atom in the Cu crystal? The electron work function of Cu is phi_(Cu)=7.44xx10^(-19) J .

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Knowledge Check

  • The electron in hydrogen atom makes a transition n_(1)ton_(2) where n_1 and n_2 are the principal quantum number of two states. Assuming the Bohr model to be valid, the time period of the electron in the initial state is eight times that in the final state. The possible value of n_1 and n_2 are:

    A
    `n_1=4,n_2=2`
    B
    `n_1=8,n_2=2`
    C
    `n_1=8,n_2=1`
    D
    `n_1=6,n_2=2`
  • The Bohr's energy of a stationary state of hydrogen atom is given as E_(n)=(-2pi^(2)me^(4))/(n^(2)h^(2)) . Putting the values of m and e for n^(th) energy level which is not the correct value?

    A
    `E_(n)=(-21.8xx10^(-19))/(n^(2))J atom^(-1)`
    B
    `E_(n)=(-13.6)/(n^(2))eV atom^(-1)`
    C
    `E_(n)=(-1312)/(n^(2))kJ mol^(-1)`
    D
    `E_(n)=(-12.8xx10^(-19))/(n^(2))erg atom^(-1)`
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