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If the equilibrium constant for the reac...

If the equilibrium constant for the reaction `0.125`.
`P_(4(g))+6Cl_(2(g))hArr4PCl_(3(g))`
The value of equilibrium constant for this reaction
`4PCl_(3(g))hArrP_(4(g))+6Cl_(2(g))`

A

`0.25`

B

`8`

C

`0.125`

D

`6`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equilibrium constant for the reaction \(4PCl_3(g) \rightleftharpoons P_4(g) + 6Cl_2(g)\) given that the equilibrium constant for the reaction \(P_4(g) + 6Cl_2(g) \rightleftharpoons 4PCl_3(g)\) is \(K_{c1} = 0.125\), we can follow these steps: ### Step-by-Step Solution: 1. **Write the Given Reaction and Its Equilibrium Constant**: The first reaction is: \[ P_4(g) + 6Cl_2(g) \rightleftharpoons 4PCl_3(g) \] The equilibrium constant for this reaction is given as: \[ K_{c1} = 0.125 \] 2. **Write the Reverse Reaction**: The reverse of the given reaction is: \[ 4PCl_3(g) \rightleftharpoons P_4(g) + 6Cl_2(g) \] 3. **Relate the Equilibrium Constants**: For any reaction, if you reverse the reaction, the equilibrium constant for the reverse reaction is the reciprocal of the equilibrium constant for the forward reaction. Therefore: \[ K_{c2} = \frac{1}{K_{c1}} \] 4. **Substitute the Value of \(K_{c1}\)**: Now, substituting the value of \(K_{c1}\): \[ K_{c2} = \frac{1}{0.125} \] 5. **Calculate \(K_{c2}\)**: Performing the calculation: \[ K_{c2} = 8 \] ### Final Answer: The equilibrium constant for the reaction \(4PCl_3(g) \rightleftharpoons P_4(g) + 6Cl_2(g)\) is: \[ K_{c2} = 8 \] ---
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RESONANCE ENGLISH-CHEMICAL EQUILIBRIUM-Advanced Level Problems (Part-3)(Stage-1)
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