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In the following benzyl/allyl system ...

In the following benzyl/allyl system

Then decreasing order of inductive effect is :

A

`(CH_(3))_(3)C-gt(CH_(3))_(2)CH-gtCH_(3)CH_(2)-`

B

`Ch_(3)CH_(2)-gt(CH_(3))_(2)CH-gt(CH_(3))_(3)C-`

C

`(CH_(3))_(2)CH-gtCH_(3)CH_(2)-gt(CH_(3))_(3)C-`

D

`(CH_(3))_(3)C-gtCH_(3)CH_(2)-gt(CH_(3))_(2)CH-`

Text Solution

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The correct Answer is:
A
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Knowledge Check

  • Inductive effect involves

    A
    displacement off `sigma`-electrons resulting in polarisation
    B
    displacement of `pi`-electrons resulting in polarisation
    C
    delocalisation of `sigma`-electrons
    D
    delocalisation of `pi`-electrons.

  • The decreasing order of stability of following cations is

    A
    `P gt Q gt R gt S`
    B
    `Q gt S gt R gt P`
    C
    `Q gt P gt S gt R`
    D
    `Q gt P gt R gt S`

  • The decreasing order of stability of following cations is

    A
    `P gt R gt Q gt S`
    B
    `Q gt R gt S gt P`
    C
    `R gt S gt Q gt P`
    D
    `P gt R gt S gt Q`