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In the Bohr's model , for unielectronic ...

In the Bohr's model , for unielectronic species following symbols are used
`r_(n,z)to` Radius of `n^"th"` orbit with atomic number "z"
`U_(n,z)to` Potential energy of electron in `n^"th"` orbit with atomic number "z"
`K_(n,z)to` Kinetic energy of electron in `n^"th"` orbit with atomic number "z"
`V_(n,z)to` Velocity of electon in `n^"th"` orbit with atomic number "z"
`T_(n,z)to` Time period of revolution of electon in `n^"th"` orbit with atomic number "z"
Calculate z in all in cases.
(i)`U_(1,2):K_(1,z)=-8:9`
(ii)`r_(1,z):r_(2,1) =1:12`
(iii)`v_(1,z):v_(3,1)=15:1`
(iv)`T_(1,2):T_(2,z)=9:32`
Report your answer as (2r-p-q-s) where p,q,r and s represents the value of "z" in parts (i),(ii),(iii),(iv).

Text Solution

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The correct Answer is:
To solve the problem, we will analyze each part (i) to (iv) step by step using the Bohr model equations for unielectronic species. ### Given Information: 1. **Bohr's Model Equations:** - Radius of nth orbit: \( r_{n,z} = \frac{n^2}{z} \cdot r_0 \) (where \( r_0 \) is a constant) - Potential energy: \( U_{n,z} = -\frac{z^2 e^4 m}{2 \hbar^2 n^2} \) - Kinetic energy: \( K_{n,z} = \frac{z^2 e^4 m}{8 \hbar^2 n^2} \) - Velocity: \( V_{n,z} = \frac{z e^2}{2 \hbar} \cdot \frac{1}{n} \) - Time period: \( T_{n,z} = \frac{2 \pi n}{V_{n,z}} \) ### Part (i): \( U_{1,2}: K_{1,z} = -8:9 \) 1. **Calculate \( U_{1,2} \) and \( K_{1,z} \):** - \( U_{1,2} = -\frac{2^2 e^4 m}{2 \hbar^2} = -\frac{4 e^4 m}{2 \hbar^2} = -\frac{2 e^4 m}{\hbar^2} \) - \( K_{1,z} = \frac{z^2 e^4 m}{8 \hbar^2} \) 2. **Set up the ratio:** \[ \frac{U_{1,2}}{K_{1,z}} = \frac{-\frac{2 e^4 m}{\hbar^2}}{\frac{z^2 e^4 m}{8 \hbar^2}} = -\frac{16}{z^2} \] Given \( -\frac{16}{z^2} = -\frac{8}{9} \) 3. **Solve for \( z \):** \[ \frac{16}{z^2} = \frac{8}{9} \implies 16 \cdot 9 = 8 z^2 \implies 144 = 8 z^2 \implies z^2 = 18 \implies z = 3 \] ### Part (ii): \( r_{1,z}: r_{2,1} = 1:12 \) 1. **Calculate \( r_{1,z} \) and \( r_{2,1} \):** - \( r_{1,z} = \frac{1^2}{z} \cdot r_0 = \frac{r_0}{z} \) - \( r_{2,1} = \frac{2^2}{1} \cdot r_0 = 4r_0 \) 2. **Set up the ratio:** \[ \frac{r_{1,z}}{r_{2,1}} = \frac{\frac{r_0}{z}}{4r_0} = \frac{1}{4z} \] Given \( \frac{1}{4z} = \frac{1}{12} \) 3. **Solve for \( z \):** \[ 12 = 4z \implies z = 3 \] ### Part (iii): \( v_{1,z}: v_{3,1} = 15:1 \) 1. **Calculate \( v_{1,z} \) and \( v_{3,1} \):** - \( v_{1,z} = \frac{z e^2}{2 \hbar} \) - \( v_{3,1} = \frac{1 e^2}{6 \hbar} \) 2. **Set up the ratio:** \[ \frac{v_{1,z}}{v_{3,1}} = \frac{\frac{z e^2}{2 \hbar}}{\frac{e^2}{6 \hbar}} = \frac{6z}{2} = 3z \] Given \( 3z = 15 \) 3. **Solve for \( z \):** \[ z = 5 \] ### Part (iv): \( T_{1,2}: T_{2,z} = 9:32 \) 1. **Calculate \( T_{1,2} \) and \( T_{2,z} \):** - \( T_{1,2} = \frac{2 \pi \cdot 1}{\frac{2 e^2}{2 \hbar}} = \frac{2 \pi \cdot 2 \hbar}{e^2} \) - \( T_{2,z} = \frac{2 \pi \cdot 2}{\frac{z e^2}{2 \hbar}} = \frac{4 \pi \cdot 2 \hbar}{z e^2} \) 2. **Set up the ratio:** \[ \frac{T_{1,2}}{T_{2,z}} = \frac{\frac{4 \pi \hbar}{e^2}}{\frac{4 \pi \cdot 2 \hbar}{z e^2}} = \frac{z}{2} \] Given \( \frac{z}{2} = \frac{9}{32} \) 3. **Solve for \( z \):** \[ z = \frac{9 \cdot 2}{32} = \frac{18}{32} = \frac{9}{16} \] ### Final Answers: - (i) \( z = 3 \) - (ii) \( z = 3 \) - (iii) \( z = 5 \) - (iv) \( z = \frac{9}{16} \) ### Reporting the Answer: The final answer is \( (2r - p - q - s) \) where \( p = 3, q = 3, r = 5, s = \frac{9}{16} \).
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