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Why heavy metal chlorides such as Hg(2)C...

Why heavy metal chlorides such as `Hg_(2)Cl_(2), AgCl, PbCl_(2)` etc. do not respond to chromyl chloride test.

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### Step-by-Step Solution: 1. **Understanding the Chromyl Chloride Test**: - The chromyl chloride test is a qualitative analysis method used to detect chloride ions (Cl⁻) in a sample. - In this test, potassium dichromate (K₂Cr₂O₇) is used in the presence of concentrated sulfuric acid (H₂SO₄). 2. **Reaction Mechanism**: - When chloride ions are present, they react with potassium dichromate and concentrated sulfuric acid to produce chromyl chloride (CrO₂Cl₂) as an orange-red vapor. ...
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S_(1) : Silver iodide is fairly soluble in hypo solution. S_(2) : Heavy metal chloride like AgCl,HgCl_(2) etc. also respond to Chromyl chloride test. S_(3) : Bromine reacts with KI liberating violet vapours of iodine. S_(4) : Diphenylamine reagent test is also given by nitrites chlorates, bromates, iodates, etc. in addition to NO_(3)^(-)

Dilute Hydrochloride acid contains Cl- ions but it does not give positive chromyl chloride test, why?

Why do alkali metals respond to flame test?

Assertion : Solid potassium dichromate gives greenish yellow vapour with concentrated H_(2) SO_(4) and solid ammonium chloride. Reason : The reaction of ammonium chloride with solide K_(2) Cr_(2) O_(7) and concentrated H_(2) SO_(4) produces chromyl chloride.

In acidic radical conc. H_(2)SO_(4) group which radical give's chromyl chloride test.

Give the correct order of initials T or F for following statements. Use T iff statement is true and F if it is false. (i) Cu^(+) undergoes disproportionation to Cu and Cu^(2+) in aqueous solution. (ii) Hg_(2)Cl_(2) does not impart chromyl chloride test (iii) Sulphide ions react with sodium nitroprusside to form a purple coloured complex. in this reaction, oxidation state of iron changes.

What is chromyl chloride test? Why is it so named?

Draw structure Sulphuryl chloride (SO_(2)Cl_(2))

Hg_2Cl_2 + NH_4OH to

Sulphur forms the chlorides S_(2)Cl_(2) and SCl_(2) . The equivalent mass of sulphur in SCl_(2) is

RESONANCE ENGLISH-QUALITATIVE ANALYSIS (ANION)-Exercise-1
  1. Dilute Hydrochloride acid contains Cl- ions but it does not give posit...

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  2. Identify the gas A, B and C.

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  3. Why heavy metal chlorides such as Hg(2)Cl(2), AgCl, PbCl(2) etc. do no...

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  4. Why is a freshly prepared solution of FeSO(4) used for the detection o...

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  5. Interfering radicals interfere the test of

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  6. In which of the following reagents, the white precipitate fo PbSO(4) i...

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  7. How will you distinguish between sulphite and sulphate ions?

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  8. A current of 2.0 A when passed for 5 hrs through a molten slat deposit...

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  9. Which of the following can evolve more than one gas (vapour) if heated...

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  10. Zinc sulphide reacts with dilute H(2)SO(4) to liberate which gas.

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  11. Which of the following metal carbonates liberate. CO(2)(g) on heating ...

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  12. In which of the following reactions a brown coloured gas is evolved ?

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  13. An electric kettle has two coils. When one of these is switched on, th...

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  14. The hottest part of the flame of a Bunsen burner is the

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  15. Metal (M) shows crimson red colour in flame test and its halide is del...

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  16. In Borax bead test, metal oxides react with B(2)O(3) and form a colour...

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  17. Which one of the following ions does not give borax bead test ?

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  18. Concrete is produced form a mixture of cement, water and small stones....

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  19. A salt gives white residue in charcoal cavity test but in cobalt nitra...

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  20. Which of the following anions are identified by dil. HCl :

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