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The angle between the bonding orbitals o...

The angle between the bonding orbitals of a molecules `AX_(3)` with zero dipole moment is

A

`120^(º)`

B

`109^(º)`

C

`104^(º)`

D

`180^(º)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the angle between the bonding orbitals of a molecule of the type AX₃ with zero dipole moment, we can follow these steps: ### Step 1: Understand the Molecular Geometry - The molecule AX₃ consists of one central atom A and three surrounding atoms X. - The presence of three identical surrounding atoms suggests a symmetrical arrangement. **Hint:** Consider the arrangement of atoms around the central atom to determine the molecular geometry. ### Step 2: Identify the Molecular Shape - For a molecule with the formula AX₃, the molecular geometry is typically trigonal planar if there are no lone pairs on the central atom A. - A trigonal planar arrangement has the three atoms X positioned at the corners of an equilateral triangle. **Hint:** Recall the VSEPR theory, which helps predict the shape of molecules based on the number of bonding and lone pairs. ### Step 3: Determine the Bond Angles - In a trigonal planar geometry, the bond angles between the surrounding atoms (X) are equal. - The ideal bond angle in a trigonal planar arrangement is 120 degrees. **Hint:** Visualize or sketch the trigonal planar structure to see how the atoms are arranged and the angles formed. ### Step 4: Consider the Dipole Moment - A zero dipole moment indicates that the molecule is non-polar. This occurs when the individual bond dipoles cancel each other out. - In the case of AX₃, if A is less electronegative than X (like in BF₃), the bond dipoles will cancel due to symmetry. **Hint:** Think about how the symmetry of the molecule affects the overall dipole moment. ### Conclusion - Therefore, the angle between the bonding orbitals of a molecule AX₃ with zero dipole moment is **120 degrees**. **Final Answer:** 120 degrees
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