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The angle between the bonding orbitals o...

The angle between the bonding orbitals of a molecules `AX_(3)` with zero dipole moment is

A

`120^(º)`

B

`109^(º)`

C

`104^(º)`

D

`180^(º)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the angle between the bonding orbitals of a molecule of the type AX₃ with zero dipole moment, we can follow these steps: ### Step 1: Understand the Molecular Geometry - The molecule AX₃ consists of one central atom A and three surrounding atoms X. - The presence of three identical surrounding atoms suggests a symmetrical arrangement. **Hint:** Consider the arrangement of atoms around the central atom to determine the molecular geometry. ### Step 2: Identify the Molecular Shape - For a molecule with the formula AX₃, the molecular geometry is typically trigonal planar if there are no lone pairs on the central atom A. - A trigonal planar arrangement has the three atoms X positioned at the corners of an equilateral triangle. **Hint:** Recall the VSEPR theory, which helps predict the shape of molecules based on the number of bonding and lone pairs. ### Step 3: Determine the Bond Angles - In a trigonal planar geometry, the bond angles between the surrounding atoms (X) are equal. - The ideal bond angle in a trigonal planar arrangement is 120 degrees. **Hint:** Visualize or sketch the trigonal planar structure to see how the atoms are arranged and the angles formed. ### Step 4: Consider the Dipole Moment - A zero dipole moment indicates that the molecule is non-polar. This occurs when the individual bond dipoles cancel each other out. - In the case of AX₃, if A is less electronegative than X (like in BF₃), the bond dipoles will cancel due to symmetry. **Hint:** Think about how the symmetry of the molecule affects the overall dipole moment. ### Conclusion - Therefore, the angle between the bonding orbitals of a molecule AX₃ with zero dipole moment is **120 degrees**. **Final Answer:** 120 degrees
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RESONANCE ENGLISH-COORDINATION COMPOUNDS-Additional Problem for Self Practice (APSP) Part-II
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  3. Ligands contains :

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  4. e(g) orbitals include

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  5. Dimethyl glyoxime forms a square planar complex with Ni^(2+) . This co...

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  6. A [M(H(2)O)(6)]^(2+) complex typically absorbs at around 600 nm. it is...

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  7. The least stable metal cabonyl as per the bonding considerations shoul...

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  8. A coordination complex of type MX(2)Y(2) (M-metal ion: X, Y-monodentat...

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  9. The compoudbin which nickel has the lowest oxidation state is :

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  10. The IUPAC name of complex K(3)[Al(C(2)O(4))] is

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  11. Geometric isomers would be expected for which of the following compoun...

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  12. Co-ordination compounds [Pt(NH(3))(3)(NCS)] and [Pt(NH(3))(2) Cl(2)]Cl...

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  13. The highest molar conductivity will be exhibited by the complex .

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  14. How many isomers are possible for the complex [Co(en)(2)Cl(2)](en=ethy...

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  15. Which of the following complex ions does satisfy the effective atomic ...

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  16. In which of the following compounds, the oxidation number of iodine is...

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  17. [NiCl(4)]^(2-) is paramagnetic and therefore its geometry is :

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  18. dsp^(2) hybridization represent

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  19. Name of the type of isomerism exhibited by the following pairs of com...

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  20. The complex pentaaminecarbonatocobalt(III) chlorides is :

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