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How many geometrical isomers are possibl...

How many geometrical isomers are possible for the given compound?
Ph-CH=CH-CH=CH-COOH

A

2

B

4

C

6

D

8

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of geometrical isomers for the compound Ph-CH=CH-CH=CH-COOH, we will follow these steps: ### Step 1: Identify the Structure The compound can be represented as follows: - Ph-CH=CH-CH=CH-COOH This indicates a phenyl group (Ph) attached to a chain with two double bonds and a carboxylic acid (COOH) at the end. ### Step 2: Analyze the Double Bonds The compound has two double bonds (C=C). Each double bond can potentially give rise to geometrical isomers (cis and trans) depending on the substituents attached to the carbons involved in the double bonds. ### Step 3: Determine Possible Isomers 1. **First Double Bond (C1=C2)**: - If both substituents (H) are on the same side, it is a cis isomer. - If the substituents are on opposite sides, it is a trans isomer. 2. **Second Double Bond (C3=C4)**: - Similarly, if both substituents (H) are on the same side, it is a cis isomer. - If the substituents are on opposite sides, it is a trans isomer. ### Step 4: Count the Combinations - For the first double bond (C1=C2), we can have: - Cis (H and Ph on the same side) - Trans (H and Ph on opposite sides) - For the second double bond (C3=C4), we can also have: - Cis (H and COOH on the same side) - Trans (H and COOH on opposite sides) ### Step 5: Combine the Isomers Now we can combine the configurations of both double bonds: 1. **Cis (C1=C2) and Cis (C3=C4)** 2. **Cis (C1=C2) and Trans (C3=C4)** 3. **Trans (C1=C2) and Cis (C3=C4)** 4. **Trans (C1=C2) and Trans (C3=C4)** Thus, we can conclude that there are a total of **4 geometrical isomers** possible for the compound Ph-CH=CH-CH=CH-COOH. ### Final Answer The total number of geometrical isomers for the given compound is **4**. ---
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