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C-C bond length is maximum in...

`C-C` bond length is maximum in

A

`C_(60)`

B

graphite

C

`C_(70)`

D

diamond

Text Solution

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The correct Answer is:
To determine which compound has the maximum C-C bond length, we need to analyze the hybridization and bonding characteristics of the given options. ### Step-by-Step Solution: 1. **Identify the Compounds**: The options provided are C60 (Buckminsterfullerene), graphite, diamond, and C70. 2. **Understand Hybridization**: - **C60 (Buckminsterfullerene)**: It has sp2 hybridization. The structure consists of carbon atoms arranged in a spherical shape, with each carbon atom forming three sigma bonds and one pi bond. - **Graphite**: It also has sp2 hybridization. In graphite, carbon atoms are arranged in layers, with each carbon forming three sigma bonds and one pi bond, resulting in a planar structure. - **Diamond**: It has sp3 hybridization. In diamond, each carbon atom forms four sigma bonds with other carbon atoms, resulting in a tetrahedral structure. - **C70**: Similar to C60, C70 has sp2 hybridization, with carbon atoms forming a structure that includes both sigma and pi bonds. 3. **Analyze Bond Lengths**: - The bond length is influenced by the type of bond formed. Single bonds (sigma bonds) are longer than double bonds (which consist of one sigma and one pi bond). - Since diamond has sp3 hybridization, it consists entirely of single C-C bonds. Therefore, it will have the longest bond length among the options provided. - In contrast, C60, graphite, and C70 contain double bonds due to their sp2 hybridization, which results in shorter bond lengths compared to single bonds. 4. **Conclusion**: Since diamond has only single C-C bonds (sp3 hybridization), it has the maximum C-C bond length compared to C60, graphite, and C70, which have double bonds (sp2 hybridization). ### Final Answer: The C-C bond length is maximum in **diamond**. ---

To determine which compound has the maximum C-C bond length, we need to analyze the hybridization and bonding characteristics of the given options. ### Step-by-Step Solution: 1. **Identify the Compounds**: The options provided are C60 (Buckminsterfullerene), graphite, diamond, and C70. 2. **Understand Hybridization**: - **C60 (Buckminsterfullerene)**: It has sp2 hybridization. The structure consists of carbon atoms arranged in a spherical shape, with each carbon atom forming three sigma bonds and one pi bond. ...
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Knowledge Check

  • Carbon-carbon double bond length will be maximum in which of the following compounds ?

    A
    `CH_3 -CH=CH_2`
    B
    `CH_3 -CH=CH-CH_3`
    C
    `CH_3-underset(CH_3)underset(|)C=underset(CH_3)underset(|)C-CH_3`
    D
    `CH_2=CH_2`
  • The most stable form of carbon at high temperature is X. The C - C bond length in diamond is Y while C - C bond length is graphite is Z. What are X,Y and Z respectively?

    A
    Graphite `1.42 Å, 1.54 Å`
    B
    Coke, `1.54 Å, 1.84 Å`
    C
    Diamond, `1.54 Å, 1.42 Å`
    D
    Fullerene, `1.54 Å, 1.54 Å`
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