Home
Class 12
CHEMISTRY
The dipole moments of NH3, NF3 and H2O a...

The dipole moments of `NH_3, NF_3` and `H_2O` are in the order.

A

`NH_3ltNF_3ltH_2O`

B

`NH_3ltNF_3=H_2O`

C

`NF_3ltNH_3ltH_2O`

D

`NF_3ltH_2OltNH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of dipole moments for the molecules NH₃ (ammonia), NF₃ (nitrogen trifluoride), and H₂O (water), we need to analyze the molecular geometry and electronegativity of the atoms involved. ### Step 1: Analyze the molecular structures - **NH₃ (Ammonia)**: The nitrogen atom is at the center with three hydrogen atoms bonded to it. The molecule has a trigonal pyramidal shape due to the presence of a lone pair on nitrogen. The dipole moments from the N-H bonds do not cancel out, resulting in a net dipole moment directed towards the nitrogen. - **NF₃ (Nitrogen Trifluoride)**: Similar to NH₃, NF₃ also has a trigonal pyramidal shape. However, the electronegativity of fluorine is higher than that of nitrogen, which means the dipole moments of the N-F bonds point towards the fluorine atoms. The dipole moments in NF₃ tend to cancel out more than in NH₃, leading to a smaller net dipole moment. - **H₂O (Water)**: Water has a bent molecular shape due to two lone pairs on the oxygen atom. The O-H bonds are highly polar due to the high electronegativity of oxygen, and the dipole moments do not cancel out. This results in a significant net dipole moment directed towards the oxygen. ### Step 2: Compare the dipole moments - **NH₃** has a significant dipole moment due to the polar N-H bonds and the geometry that does not allow for cancellation. - **H₂O** has an even larger dipole moment because of the bent shape and the high electronegativity of oxygen. - **NF₃** has the smallest dipole moment because the dipole moments of the N-F bonds largely cancel each other out. ### Conclusion Based on the analysis: - The order of dipole moments is: **H₂O > NH₃ > NF₃**. ### Final Answer The correct order of dipole moments is **H₂O > NH₃ > NF₃**. ---

To determine the order of dipole moments for the molecules NH₃ (ammonia), NF₃ (nitrogen trifluoride), and H₂O (water), we need to analyze the molecular geometry and electronegativity of the atoms involved. ### Step 1: Analyze the molecular structures - **NH₃ (Ammonia)**: The nitrogen atom is at the center with three hydrogen atoms bonded to it. The molecule has a trigonal pyramidal shape due to the presence of a lone pair on nitrogen. The dipole moments from the N-H bonds do not cancel out, resulting in a net dipole moment directed towards the nitrogen. - **NF₃ (Nitrogen Trifluoride)**: Similar to NH₃, NF₃ also has a trigonal pyramidal shape. However, the electronegativity of fluorine is higher than that of nitrogen, which means the dipole moments of the N-F bonds point towards the fluorine atoms. The dipole moments in NF₃ tend to cancel out more than in NH₃, leading to a smaller net dipole moment. - **H₂O (Water)**: Water has a bent molecular shape due to two lone pairs on the oxygen atom. The O-H bonds are highly polar due to the high electronegativity of oxygen, and the dipole moments do not cancel out. This results in a significant net dipole moment directed towards the oxygen. ...
Promotional Banner

Topper's Solved these Questions

  • JEE MAIN REVISION TEST - 28

    VMC MODULES ENGLISH|Exercise CHEMISTRY (SECTION-2)|5 Videos
  • JEE MAIN REVISION TEST - 4 JEE - 2020

    VMC MODULES ENGLISH|Exercise CHEMISTRY|25 Videos

Similar Questions

Explore conceptually related problems

The dipole moments of CCl _ 4, CHCl _ 3 and CH _ 4 are in the order :

The dipole moments of CCl _ 4, CHCl _ 3 and CH _ 4 are in the order :

The bond angles in NH_(3), NF_(3) and NCl_(3) are in the order:

The correct order of dipole moments of HF, H_(2)S and H_(2)O is :

The dipole moments of CH_(3)Cl , CH_(2)Cl_(2), CHCl_(3) are in the order

The dipoles moment of NF_(3) is less than NH_(3) because

The electronegaivity difference between N and F is greater than that between N and H yet the dipole moment of NH_3 ( 1 .5 D) is larger than that of NF_3 ( 0. 2 D) . This is because :

The dipole moment of o, p and m-dichlorobenzene will be in the order :

Correct dipole moment order is

VMC MODULES ENGLISH-JEE MAIN REVISION TEST - 29 (2020)-CHEMISTRY
  1. Styrene when treated with HBr produces :

    Text Solution

    |

  2. A mixture of phenol and aromatic carboxylic acid can be separated easi...

    Text Solution

    |

  3. The number of orbitals associated with quantum numbers n =4 and m (8) ...

    Text Solution

    |

  4. Oxidation number of oxygen in K2O,K2O2 and KO2 respectively is :

    Text Solution

    |

  5. Text Solution

    |

  6. The atomic radius of Ru is closet to

    Text Solution

    |

  7. When zeolite which is hydrated sodium aluminium silicate is treated wi...

    Text Solution

    |

  8. Ellingham diagram represents change of

    Text Solution

    |

  9. The dipole moments of NH3, NF3 and H2O are in the order.

    Text Solution

    |

  10. The electron gain enthalpy (in kJ/mole) of F, O, N and C respectively ...

    Text Solution

    |

  11. What is the final product of following reaction ? Isopropyl alcohol ...

    Text Solution

    |

  12. The weakest inter molecular forces are present in:

    Text Solution

    |

  13. Consider the following reaction : The product 'X' is used :

    Text Solution

    |

  14. The increasing order of pKb for the following compounds will be :

    Text Solution

    |

  15. In which of the following coordination entities the magnitude of Delta...

    Text Solution

    |

  16. The number of oxygen atom in paracetamol is …..

    Text Solution

    |

  17. Two solution A and B, each of 80L was made by dissolving 4 gm NaOH and...

    Text Solution

    |

  18. Two radioactive nuclides A and B have half-lives 50 min and 10 min res...

    Text Solution

    |

  19. For the reaction, Ag2O(s)to2Ag(s)+1/2O2(g),/\H,/\S and T are 40kJ, 100...

    Text Solution

    |

  20. A colorless inorganic compound impart a green color to flame. It’s sol...

    Text Solution

    |