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C-O-C bond angle in diethyl ether is abo...

`C-O-C` bond angle in diethyl ether is about-

A

`180^(@)`

B

`110^(@)`

C

`150^(@)`

D

`90^(@)`

Text Solution

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The correct Answer is:
To determine the C-O-C bond angle in diethyl ether, we can follow these steps: ### Step 1: Understand the Structure of Diethyl Ether Diethyl ether (C2H5)2O has the following structure: - It consists of an oxygen atom bonded to two ethyl groups (C2H5). - The molecular formula can be represented as CH3-CH2-O-CH2-CH3. ### Step 2: Identify the Hybridization of the Oxygen Atom - The oxygen atom in diethyl ether is bonded to two carbon atoms and has two lone pairs of electrons. - This results in a tetrahedral arrangement around the oxygen atom due to sp³ hybridization. ### Step 3: Determine the Expected Bond Angle - In a perfect tetrahedral structure, the bond angles are approximately 109.5°. - However, the presence of lone pairs can affect the bond angles. ### Step 4: Analyze the Effect of Lone Pairs - The two lone pairs on the oxygen atom create repulsion, which can push the bonded atoms closer together. - This results in a slight increase in the bond angle from the ideal tetrahedral angle. ### Step 5: Conclude the Bond Angle - In diethyl ether, the C-O-C bond angle is observed to be about 110° due to the repulsion between the lone pairs and the bonded pairs. - Therefore, the answer to the question is that the C-O-C bond angle in diethyl ether is approximately 110°. ### Final Answer: The C-O-C bond angle in diethyl ether is about **110°**. ---
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The C-C-H bond angle in ethylene is:

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Knowledge Check

  • The C-O-C angle in ether is about

    A
    `180^(@)`
    B
    `190^(@) 28`
    C
    `110 ^(@)`
    D
    `105^(@)`
  • Diethyl ether is soluble in

    A
    Water
    B
    Dilute HCl
    C
    Conc. `H_(2)SO_(4)`
    D
    Conc. KOH
  • Why is the C-O-H bond angle in alcohols slightly less than the tetrahedral angle whereas the C-O-C bond angle in ether is slightly greater?

    A
    of repulsion between the two bulky R groups .
    B
    O atom in both alcohols and ethers is `sp^(3)`-hybridised .
    C
    lone pair-lone pair repulsion is greater than bond pair - bond pair repulsion .
    D
    none of these
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