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In trimethylamine, the nitrogen has a py...

In trimethylamine, the nitrogen has a pyramidal geometry whereas in trisilylamine `N(SiH_(3)) _(3),` it has a planar geometry. What is the reaons behind this ?

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**Step-by-Step Text Solution:** 1. **Understanding the Molecules**: - We need to analyze the molecular structures of trimethylamine (N(CH₃)₃) and trisilylamine (N(SiH₃)₃). - Trimethylamine has nitrogen bonded to three methyl groups (CH₃), while trisilylamine has nitrogen bonded to three silyl groups (SiH₃). 2. **Geometry of Trimethylamine**: - In trimethylamine, the nitrogen atom has one lone pair of electrons and forms three sigma bonds with the three methyl groups. ...
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Knowledge Check

  • The BCl_3 is a planar molecule whereas NCl_3 is pyramidal because

    A
    B-Cl bond is more polar than N - Cl bond
    B
    N-Cl bond is more covalent than B- Cl bond
    C
    nitrogen atom is smaller than boron atoms
    D
    `BCl_(3)` has no lone pair but `NCl_(3)` has a lone pair of electrons.
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