Home
Class 12
CHEMISTRY
A molecule XY2 contains two sigma, two p...

A molecule `XY_2` contains two `sigma`, two `pi` and one lone pair of electron in valence shell of X. The arrangement of lone pair as well as bond pairs is

A

square pyramidal

B

linear

C

trigonal planar

D

unpredictable

Text Solution

AI Generated Solution

The correct Answer is:
To determine the arrangement of lone pairs and bond pairs in the molecule `XY2`, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Number of Electrons:** - The molecule `XY2` has 2 sigma bonds, 2 pi bonds, and 1 lone pair of electrons in the valence shell of atom X. - Each sigma bond is formed by 2 electrons, and each pi bond is formed by 2 electrons as well. - Therefore, the total number of electrons involved is: - 2 (from sigma bonds) + 2 (from pi bonds) + 1 (from the lone pair) = 5 electrons. 2. **Determine the Group of Element X:** - Since the total number of valence electrons is 6, element X must belong to group 16 of the periodic table (which includes elements like oxygen, sulfur, etc.). 3. **Analyze the Structure:** - A common example of a molecule with this configuration is sulfur dioxide (SO2). - In SO2, sulfur (S) is the central atom (X), bonded to two oxygen atoms (Y). - The structure can be visualized as: - S has 2 sigma bonds with O and 2 pi bonds (one for each O), and 1 lone pair. 4. **Determine Hybridization:** - The steric number is calculated as the sum of sigma bonds and lone pairs: - Steric number = Number of sigma bonds + Number of lone pairs = 2 + 1 = 3. - This indicates that the hybridization of X is sp². 5. **Determine Molecular Geometry:** - With a steric number of 3 and one lone pair, the molecular geometry is trigonal planar. - However, due to the presence of the lone pair, the actual shape becomes bent (or V-shaped). 6. **Conclusion:** - The arrangement of lone pairs and bond pairs in the molecule `XY2` is such that it has a bent shape due to the repulsion between the lone pair and the bonding pairs. ### Final Answer: The arrangement of lone pairs and bond pairs in the molecule `XY2` is a bent shape due to the presence of one lone pair and two bond pairs.

To determine the arrangement of lone pairs and bond pairs in the molecule `XY2`, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Number of Electrons:** - The molecule `XY2` has 2 sigma bonds, 2 pi bonds, and 1 lone pair of electrons in the valence shell of atom X. - Each sigma bond is formed by 2 electrons, and each pi bond is formed by 2 electrons as well. - Therefore, the total number of electrons involved is: ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING & MOLECULAR STRUCTURE

    VMC MODULES ENGLISH|Exercise PRACTICE EXERCISE|36 Videos
  • CHEMICAL BONDING & MOLECULAR STRUCTURE

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-A|10 Videos
  • CHEMICAL BONDING & MOLECULAR STRUCTURE

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-L|9 Videos
  • CHEMICAL BONDING & CHEMICAL STRUCTURE

    VMC MODULES ENGLISH|Exercise IMPECCABLE|50 Videos
  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|98 Videos

Similar Questions

Explore conceptually related problems

A molecule XY_(2) contains two sigma bonds two pi bond and one lone pair of electrons in the valence shell of X . The arrangement of lone pair as well as bond pairs is

A molecule XY_(2) contains two sigma bonds two pi bond and one lone pair of electrons in the valence shell of X . The arrangement of lone pair as well as bond pairs is

What is a lone pair of electrons ?

A compound having one lone pair of electrons :

Total number of lone pair of electrons in XeOF_4 is :

Total number of lone pair of electrons in XeOF_4 is :

The total number of lone-pairs of electrons in melamine is.

The molecules which contain sigma bond , pi bond and lone pair 1:1:1 ratio :-

VMC MODULES ENGLISH-CHEMICAL BONDING & MOLECULAR STRUCTURE -SOLVED EXAMPLES
  1. Which of the following substance has the highest melting point? .

    Text Solution

    |

  2. Zeise's salt contains which type of bonds ?

    Text Solution

    |

  3. Which is distilled first ?

    Text Solution

    |

  4. Which factor is most responsible for the increase in boiling points of...

    Text Solution

    |

  5. Which of the following resonating structures is not correct for CO(2) ...

    Text Solution

    |

  6. Which of the following does not contain any coordinate bond ?

    Text Solution

    |

  7. In which of the following species the angle around the central atom is...

    Text Solution

    |

  8. Arrange the following in decreasing order of dipole moment (1) m-Dich...

    Text Solution

    |

  9. In which of the following diatomjic molecules/ions is the bond order o...

    Text Solution

    |

  10. Bond order of N-O bonds in nitrate ion is

    Text Solution

    |

  11. Which of the following is paramagnetic ?

    Text Solution

    |

  12. Among LiCl, RbCl, BeCl2, MgCl2, the compounds with greatest and least ...

    Text Solution

    |

  13. Which of the following molecular orbitals has two nodal planes ?

    Text Solution

    |

  14. In PO(4)^(3-) the formal charge on each O-atom and P-O bond order resp...

    Text Solution

    |

  15. Among the following ions the ppi-dpi overlap could be present in

    Text Solution

    |

  16. Which of the following molecules is linear ?

    Text Solution

    |

  17. Which of the following hydride is ionic ?

    Text Solution

    |

  18. A covalent molecole AB(4) (not a complex) will have which of the follo...

    Text Solution

    |

  19. How many type of bond lengths are there in SO(3) ^(2-) ?

    Text Solution

    |

  20. A molecule XY2 contains two sigma, two pi and one lone pair of electro...

    Text Solution

    |