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Which bond angle, theta would result in ...

Which bond angle, `theta` would result in the maximum dipole moment for the triatomic molecule `XY_2` ?

A

`theta =90^(@)`

B

`theta = 120^(@)`

C

`theta =150^(@)`

D

`theta = 180^(@)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which bond angle \( \theta \) would result in the maximum dipole moment for the triatomic molecule \( XY_2 \), we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Structure of \( XY_2 \)**: - The molecule \( XY_2 \) consists of one central atom \( X \) and two identical atoms \( Y \) bonded to it. The arrangement of these atoms can affect the dipole moment. 2. **Defining the Dipole Moment**: - The dipole moment \( \mu \) of a molecule can be expressed in terms of the bond lengths and the angle between the bonds. For the molecule \( XY_2 \), the dipole moment can be represented as: \[ \mu = \sqrt{\mu_1^2 + \mu_2^2 + 2 \mu_1 \mu_2 \cos(\theta)} \] - Here, \( \mu_1 \) and \( \mu_2 \) are the dipole moments associated with each \( Y \) atom, and \( \theta \) is the bond angle between the two \( Y \) atoms. 3. **Analyzing the Effect of the Bond Angle**: - As the bond angle \( \theta \) varies, the cosine of the angle \( \cos(\theta) \) will also change. Specifically: - At \( \theta = 90^\circ \), \( \cos(90^\circ) = 0 \). - As \( \theta \) increases from \( 90^\circ \) to \( 180^\circ \), \( \cos(\theta) \) becomes negative. 4. **Finding the Maximum Dipole Moment**: - The dipole moment \( \mu \) is maximized when the contributions from the two dipole moments are as additive as possible. This occurs when \( \theta = 90^\circ \) because at this angle, the two dipole moments are perpendicular to each other, leading to maximum vector addition. 5. **Conclusion**: - Therefore, the bond angle \( \theta \) that results in the maximum dipole moment for the triatomic molecule \( XY_2 \) is: \[ \theta = 90^\circ \] ### Final Answer: The bond angle \( \theta \) that would result in the maximum dipole moment for the triatomic molecule \( XY_2 \) is \( 90^\circ \). ---
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Knowledge Check

  • Which bond angle would result in the maximum dipole moment for the triatomic molecule YXY ?

    A
    `theta= 90^@ `
    B
    ` theta =120^@ `
    C
    ` theta = 150^@`
    D
    ` theta = 180^@`
  • Which has maximum dipole moment ?

    A
    B
    C
    D
  • Which of the following molecules has the maximum dipole moment?

    A
    `CO_2 `
    B
    `CH_4`
    C
    `NH_3`
    D
    `NF_3`
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