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Glucose + Tollen's reagent to silver mir...

Glucose + Tollen's reagent `to` silver mirror. The process shows:

A

Presence of acidic group

B

Presence of alkaline group

C

Presence of ketonic group

D

Presence of aldehyde group

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To solve the question regarding the reaction of glucose with Tollen's reagent and the formation of a silver mirror, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant in this case is glucose, which is a simple sugar (monosaccharide). 2. **Understand Tollen's Reagent**: - Tollen's reagent is a solution of silver nitrate (AgNO3) in ammonia (NH3). It is used to test for the presence of aldehyde groups in compounds. 3. **Structure of Glucose**: - The molecular structure of glucose can be represented as: \[ \text{C}_6\text{H}_{12}\text{O}_6 \] - In its open-chain form, glucose has an aldehyde group (-CHO) at one end of the molecule. 4. **Reaction with Tollen's Reagent**: - When glucose (which contains an aldehyde group) reacts with Tollen's reagent, the aldehyde group is oxidized to a carboxylic acid group, forming gluconic acid. - The reaction can be summarized as: \[ \text{Glucose} + \text{Tollen's reagent} \rightarrow \text{Gluconic acid} + \text{Ag (s)} \text{ (silver mirror)} \] 5. **Formation of Silver Mirror**: - The reduction of silver ions (Ag+) to metallic silver (Ag) results in the formation of a silver mirror on the surface of the reaction vessel. 6. **Conclusion**: - The formation of a silver mirror indicates the presence of an aldehyde group in glucose. Therefore, the process shows the presence of an aldehyde group. ### Final Answer: The process shows the presence of an aldehyde group in glucose.
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Knowledge Check

  • Tollens' reagent is

    A
    Alkaline mercuric chloride solution
    B
    Ammoniacal silver nitrate solution
    C
    Ammonium citrate solution
    D
    Alkaline potassium permanganate solution.
  • Tollens' reagent is

    A
    Alkaline mercuric chloride solution
    B
    Ammoniacal silver nitrate solution
    C
    Ammonium citrate solution
    D
    Alkaline potassium permanganate solution.
  • Tollens' reagent is

    A
    Alkaline mercuric chloride solution
    B
    Ammoniacal silver nitrate solution
    C
    Ammonium citrate solution
    D
    Alkaline potassium permanganate solution.
  • Similar Questions

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    What is Tollen's reagent?

    The molecular formula of a compound (A) is C_(3)H_(7)NO . The Compound (A) hydrolyss to give an acid (B) and an amine (C ). Amine (C ) reacts with reagent ( X) to give a product insoluble in KOH. (C ) also gives nitrosoamines on reaction with HNO_(2) . Acid (B) reduces Tollen's reagent to give silver mirror. Acid B in this reaction is

    A compound is heated with zinc dust and ammonium chloride followed by addition of the Tollen's reagent. Formation of silver mirror indicates the presence of following group

    Assertion (A) Aldehydes and ketones, both react with Tollen's reagent to form silver mirror. Reason (R) Both, aldehydes and ketones contain a carbonyl group.

    When fructose treated with Tollen's reagent, silver mirror is formed due to reduction of Ag^(o+) by: