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Hydrolysis of an ester gives a carboxyli...

Hydrolysis of an ester gives a carboxylic acid which on Kolbe's electrolysis yields ethane. The ester is `:`

A

Ethyl methanoate

B

methyl ethanoate

C

Propylamine

D

Ethylamine

Text Solution

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The correct Answer is:
To solve the problem, we need to identify the ester that, upon hydrolysis, yields a carboxylic acid which can then undergo Kolbe's electrolysis to produce ethane (C2H6). ### Step-by-Step Solution: 1. **Understanding Hydrolysis of an Ester**: - The hydrolysis of an ester involves the reaction with water (H2O) to produce a carboxylic acid and an alcohol. The general reaction can be represented as: \[ RCOOR' + H2O \rightarrow RCOOH + R'OH \] - Here, RCOOR' is the ester, RCOOH is the carboxylic acid, and R'OH is the alcohol. 2. **Identifying the Product from Kolbe's Electrolysis**: - Kolbe's electrolysis involves the electrolysis of a carboxylic acid or its salt, leading to the formation of radicals. When the carboxylic acid undergoes Kolbe's electrolysis, it can lead to the formation of alkanes. - The problem states that the product of Kolbe's electrolysis is ethane (C2H6). This means that the carboxylic acid formed from the ester must have two carbon atoms. 3. **Finding the Suitable Ester**: - Since the carboxylic acid must have two carbon atoms, we can deduce that the ester we are looking for must be derived from acetic acid (CH3COOH). - The simplest ester that can be formed from acetic acid is methyl acetate (methyl ethanoate), which has the structure: \[ CH3COOCH3 \] 4. **Hydrolysis of Methyl Acetate**: - When methyl acetate is hydrolyzed, it produces acetic acid and methanol: \[ CH3COOCH3 + H2O \rightarrow CH3COOH + CH3OH \] 5. **Kolbe's Electrolysis of Acetic Acid**: - Upon performing Kolbe's electrolysis on acetic acid (CH3COOH), the reaction leads to the formation of ethane (C2H6) through the decarboxylation process: \[ 2 CH3COO^- \rightarrow C2H6 + 2 CO2 \] - Here, two acetate ions (CH3COO^-) lose carbon dioxide (CO2) to form ethane. 6. **Conclusion**: - Therefore, the ester that fits the criteria given in the question is **methyl acetate (methyl ethanoate)**. ### Final Answer: The ester is **methyl acetate (methyl ethanoate)**.
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