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If a salt bridge is removed between the ...

If a salt bridge is removed between the half cells, the voltage:

A

drops to zero

B

does not change

C

increase gradually

D

increases rapidly

Text Solution

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The correct Answer is:
To solve the question regarding the effect of removing a salt bridge between half cells in an electrochemical cell, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Role of the Salt Bridge**: - The salt bridge connects the oxidation and reduction half-cells in an electrochemical cell. It allows ions to flow between the two half-cells, which helps maintain electrical neutrality. **Hint**: Recall that the salt bridge is essential for ion flow and maintaining charge balance in the cell. 2. **Effect of Removing the Salt Bridge**: - When the salt bridge is removed, there is no longer a pathway for ions to move between the half-cells. This leads to an accumulation of charge: one half-cell may become positively charged while the other becomes negatively charged. **Hint**: Think about what happens to the charges in each half-cell when there is no ion movement. 3. **Consequences of Charge Accumulation**: - The accumulation of positive and negative charges in the half-cells will create an electric field that opposes further electron flow. This prevents the redox reactions from continuing. **Hint**: Consider how charge buildup affects the flow of electrons and the overall reaction in the cell. 4. **Voltage and Electrical Production**: - Since the flow of electrons is essential for the production of voltage in an electrochemical cell, the cessation of this flow due to charge accumulation means that the voltage will drop. **Hint**: Remember that voltage is a measure of the potential difference created by the flow of electrons. 5. **Conclusion**: - As a result of the above points, we conclude that if the salt bridge is removed, the voltage of the cell drops to zero because the electrochemical reactions cannot proceed without the movement of ions to maintain charge balance. **Final Answer**: The correct option is that the voltage drops to zero. ### Summary of the Answer: When the salt bridge is removed from an electrochemical cell, the voltage drops to zero due to the accumulation of charge in the half-cells, which prevents further reactions and the flow of electricity.
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