Home
Class 12
CHEMISTRY
A certain reaction has a Delta H of 12 k...

A certain reaction has a `Delta H` of 12 kJ and a `Delta S` of 40 `"JK"^(-1)`. The temperature above which the reaction becomes spontaneous is

A

27°C

B

27 K

C

300°C

D

30°C

Text Solution

Verified by Experts

The correct Answer is:
A

A reaction will be spontaneous, if
`Delta H - T Delta S = -"ve" or "Delta H - T Delta S lt 0`
or `T lt (Delta H)/( Delta S)`
Now, `(Delta H)/( Delta S) = (12 xx 10^3)/( 40) = 300 "K"`
`therefore` Above `27^(@)`C, the reaction becomes spontaneous.
Promotional Banner

Similar Questions

Explore conceptually related problems

For the reaction 2A+B rarr C at 298 K, DeltaH=400kJ mol^-1 and DeltaS=0.2 kJk^-1mol^_1 . At what temperature will be reaction become spontaneous considering DeltaH and DeltaS to be constant over the temperature range.

Most of the naturally occuring processes are spontaneous. Find the temperature above which the reaction, MgO(s) + C(s) rarr Mg(s) + CO(g) becomes spontaneous. (Given Delta_rH^@ = 490 kJ//mol and Delta_rS^@ = 198 J//molK )

Most of the naturally occurring processes are spontaneous. a) Give the criteria for spontaneity of a process in terms of free energy change ( DeltaG ) b) Exothermic reactions associated with a decrease in entropy are sponaneous at lower temperatures. Justify on the basis of Gibbs equation. c) Find the temperature above which the reactin MgO_((s))+C_((s))rightarrow Mg_((s))+CO_((g)) becomes spontaneous. (Given ( Delta_rH^theta=490kJmol^-1 & Delta_rS^theta=198JK mol^-1 )